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Syntheses and structural characterization of inifinite coordination polymers from bipyridyl ligands and zinc salts

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Abstract

The reaction of ZnSiF6·6H2O with 4,4′-dipyridyldisulfide (4-PDS) in CH3OH afforded the complex [Zn(4-PDS)2(SiF6)·3CH3OH] n , 1, while the reaction of Zn(ClO4)2·6H2O with l,2-bis(4-pyridyl)ethane (bpa) in CH3OH gave the complex [Zn(bpa)2(ClO4)2·CH3OH] n , 2. The 4-DPS ligand in 1 is coordinated to the metal centers through both nitrogen atoms to form a 3-D open channel and the distorted octahedral coordination geometry at each zinc center is completed by a pair of trans-F-bonded hexafluorosilicate molecule. Compound 2, the channel-type 1-D chains are interlinked through C–H···O interaction to form 3-D structure with large cavities that are occupied by the methanol molecules.

Optical antipodes of 4,4′-dipyridyldisulfide (4-PDS) and anti-and gauche-conformation of 1,2-bis(4-pyridyl)ethane (bpa)

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Acknowledgements

The researchers wish to thank the Nanya Institute of Technology and the National Science Council of the Republic of China for support.

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Authors and Affiliations

  1. Department of Textile Science, Nanya Institute of Technology, Chung-Li, R.O.C., Taiwan

    Maw-Cherng Suen

  2. Department of Chemistry, Soochow University, Taipei, R.O.C., Taiwan

    Ju-Chun Wang

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  1. Maw-Cherng Suen
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Correspondence to Maw-Cherng Suen.

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Suen, MC., Wang, JC. Syntheses and structural characterization of inifinite coordination polymers from bipyridyl ligands and zinc salts. Struct Chem 17, 315–322 (2006). https://doi.org/10.1007/s11224-006-9049-6

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