We have shown the high efficiency of using podand complexes (open-chain analogs of crown-ethers) for the inhibition of corrosion of structural iron alloys in neutral aqueous solutions. We have proposed a mechanism for the control of the rate of spontaneous electrode processes on steel by complexes of zinc with modified podands.
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References
Yu. I. Kuznetsov, “Physicochemical aspects of the inhibition of metal corrosion in aqueous solutions,” Usp. Khim., 73, No. 1, 79– 93 (2004).
D. A. Tkalenko, A. O. Omel’chuk, Yu. P. Vyshnevs’ka, and N. M. Kompanichenko, “Complexing agents of analytical chemistry as inhibitors of metal corrosion,” Ukr. Khim. Zh., 75, No. 7. 52–56 (2009).
O. S. Shepelenko, V. H. Shtamburh, V. B. Distanov, et al., “Podands as corrosion inhibitors in aqueous solutions,” Vopr. Khim. Khim. Tekhnol., No. 4(2), 289–292 (2011).
O. S. Shepelenko, N. D. Salhnenko, V. G. Shtamburg, et al., “Theoretical preconditions of the use of podands as corrosion inhibitors,” in: Bull. “Kharkiv Polytechnic Institute” Nat. Techn. Univ. [in Ukrainian], Issue 31 (2011), pp. 64–67.
Yu. I. Kuznetsov and T. P. Bardasheva, “Inhibitors of metal corrosion based on complexones. Rust protection of aluminum alloys by zinc phosphonates,” Zashch. Met., 24, No. 2, 234–240 (1988).
Testing of Cooling Liquids for Reciprocating Internal Combustion Engines: DSTU 28084-94 [in Ukrainian], Derzhspozhyvstandart Ukrainy, Kyiv (1994).
V. P. Chivruk, S. H. Polyakov, and Yu. S. Herasymenko, Electrochemical Monitoring of Anthropogenic Media [in Ukrainian], Akademperiodyka, Kyiv (2007).
M. D. Sakhnenko, M. V. Ved’, O. S. Shepelenko, et al., Inhibitor of Corrosion and Scaling [in Ukrainian], Patent of Ukraine No. 45971, IPC С23F 11/04, С23F 11/08, Publ. 10.12.2009, Bull. No. 23.
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Translated from Fizyko-Khimichna Mekhanika Materialiv, Vol.48, No.2, pp.77–80, March–April, 2012.
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Shepelenko, O.S., Sakhnenko, M.D., Shtamburh, V.H. et al. Formation of Nanoscale Protective Coatings on Iron Alloys from Podand-Containing Solutions. Mater Sci 48, 203–207 (2012). https://doi.org/10.1007/s11003-012-9492-z
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DOI: https://doi.org/10.1007/s11003-012-9492-z