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Synergistic extraction of sodium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol

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Abstract

Solvent extraction of microamounts of sodium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of dodecaethylene glycol (DDEG, L) has been investigated. The equilibrium data have been explained assuming that the species HL+, H2L2+, NaL+ and NaHL2+ (L = DDEG) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water have been determined.

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References

  1. Makrlík E, Vaňura P (1985) Talanta 32:423

    Article  Google Scholar 

  2. Makrlík E, Vaňura P, Selucký P (2009) J Solut Chem 38:1129

    Article  Google Scholar 

  3. Makrlík E, Vaňura P, Selucký P (2010) Acta Chim Slov 57:470

    Google Scholar 

  4. Toman P, Makrlík E, Vaňura P, Kašička V (2011) Z Phys Chem 225:265

    Article  CAS  Google Scholar 

  5. Makrlík E, Budka J, Vaňura P (2011) Z Phys Chem 225:271

    Article  Google Scholar 

  6. Makrlík E, Vaňura P, Sedláková Z (2009) J Radioanal Nucl Chem 280:607

    Article  Google Scholar 

  7. Makrlík E, Vaňura P, Selucký P (2010) J Radioanal Nucl Chem 283:571

    Article  Google Scholar 

  8. Makrlík E, Vaňura P, Selucký P (2010) J Radioanal Nucl Chem 284:137

    Article  Google Scholar 

  9. Romanovskiy VN, Smirnov IV, Babain VA, Todd TA, Herbst RS, Law JD, Brewer KN (2001) Solvent Extr Ion Exch 19:1

    Article  CAS  Google Scholar 

  10. Law JD, Herbst RS, Todd TA, Romanovskiy VN, Babain VA, Esimantovskiy VM, Smirnov IV, Zaitsev BN (2001) Solvent Extr Ion Exch 19:23

    Article  CAS  Google Scholar 

  11. Herbst RS, Peterman DR, Tillotson RD, Delmau LH (2008) Solvent Extr Ion Exch 26:163

    Article  CAS  Google Scholar 

  12. Zalupski PR, Herbst RS, Delmau LH, Martin LR, Peterman DR, Nash KL (2010) Solvent Extr Ion Exch 28:161

    Article  CAS  Google Scholar 

  13. Herbst RS, Peterman DR, Zalupski PR, Nash KL, Tillotson RD, Delmau LH (2010) Solvent Extr Ion Exch 28:563

    Article  CAS  Google Scholar 

  14. Vaňura P, Makrlík E, Rais J, Kyrš M (1982) Collect Czechoslov Chem Commun 47:1444

    Article  Google Scholar 

  15. Hawthorne MF, Young DC, Andrews TD, Howe DV, Pilling RL, Pitts AD, Reintjes M, Warren LF, Wegner PA (1968) J Am Chem Soc 90:879

    Article  CAS  Google Scholar 

  16. Makrlík E (1992) Collect Czechoslov Chem Commun 57:289

    Article  Google Scholar 

  17. Valentová Z, Vaňura P, Makrlík E (2006) J Radioanal Nucl Chem 267:237

    Article  Google Scholar 

  18. Vaňura P, Makrlík E (1993) Collect Czechoslov Chem Commun 58:1324

    Article  Google Scholar 

  19. Sillén LG, Warnqvist B (1969) Arkiv Kemi 31:315

    Google Scholar 

  20. Rais J, Šebestová E, Selucký P, Kyrš M (1976) J Inorg Nucl Chem 38:1742

    Article  CAS  Google Scholar 

  21. Vaňura P, Rais J, Selucký P, Kyrš M (1979) Collect Czechoslov Chem Commun 44:157

    Article  Google Scholar 

  22. Rais J (1971) Collect Czechoslov Chem Commun 36:3253

    Article  CAS  Google Scholar 

  23. Makrlík E, Vaňura P, Selucký P (2011) J Radioanal Nucl Chem 290:307

    Article  Google Scholar 

  24. Makrlík E, Vaňura P, Selucký P, J Radioanal Nucl Chem, in press

  25. Makrlík E, Vaňura P, Selucký P, Acta Chim Slov, in press

Download references

Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society,” and by the Czech Ministry of Education, Youth, and Sports, Project MSM 6046137307.

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic

    E. Makrlík

  2. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    P. Vaňura

  3. Nuclear Research Institute, 250 68, Řež, Czech Republic

    P. Selucký

Authors
  1. E. Makrlík
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  2. P. Vaňura
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  3. P. Selucký
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Correspondence to E. Makrlík.

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Makrlík, E., Vaňura, P. & Selucký, P. Synergistic extraction of sodium into nitrobenzene by using hydrogen dicarbollylcobaltate and dodecaethylene glycol. J Radioanal Nucl Chem 297, 115–118 (2013). https://doi.org/10.1007/s10967-012-2317-6

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  • DOI: https://doi.org/10.1007/s10967-012-2317-6

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