Skip to main content
Log in

Comparison of cadmium sulfide thin films deposited on glass and polyethylene terephthalate substrates with thermal evaporation for solar cell applications

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

Cadmium sulfide (CdS) thin films have been deposited onto glass and polyethylene terephthalate (PET) substrates at room temperature with thermal evaporation in a vacuum of about 3 × 10−5 Torr for use as window materials for solar cells. Effects of substrate types on the structural and optical characteristics of the films were studied. Sets of experiments were conducted to optimize the deposition of CdS films with appropriate deposition parameters. The deposited films were analyzed with atomic force microscopy, energy dispersive X-ray, X-ray diffraction and optical transmittance measurements to determine their structural and optical characteristics. X-ray diffraction patterns confirm the proper phase formation of the CdS. PET substrate exhibited the larger roughness than that for the glass because of large particles adsorbed on the PET substrate. The average transmittance of the films PET is about 71% and increases up to 81% for glass substrate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. K.D. Dobson, I. Visoly-Fisher, G. Hodes, D. Cahen, Stability of CdTe/CdS thin-film solar cells. Sol. Energy Mater. Sol. Cells 62, 295–325 (2000)

    Article  CAS  Google Scholar 

  2. R.L.N. Chandrakanthi, M.A. Careem, Preparation and characterization of CdS and Cu2S nanoparticle/polyaniline composite films. Thin Solid Films 417, 51–56 (2002)

    Article  CAS  Google Scholar 

  3. V.K. Kapur, B.M. Basol, E.S. Tseng, Low cost methods for the production of semiconductor films for CuInSe2/CdS solar cells. Solar Cells 21, 65–72 (1987)

    Google Scholar 

  4. M. Purica, E. Budianu, E. Rusu, P. Arabadji, Electrical properties of the CdS/InP heterostructures for photovoltaic applications. Thin Solid Films 511–512, 468–472 (2006)

    Article  Google Scholar 

  5. O.A. Ileperuma, C. Vithana, K. Premaratne, S.N. Akuranthilaka, S.M. Mcgreg, I.M. Dharmadasa, Comparison of CdS thin films prepared by different techniques for applications in solar cells as window materials. Mater. Sci. Mater. Electron. 9, 367–372 (1998)

    Article  CAS  Google Scholar 

  6. A.E. Rakhshani, A.S. Al-Azab, Characterization of CdS films prepared by chemical-bath deposition. J. Phys. Condens. Matter. 12, 8745–8755 (2000)

    Article  CAS  Google Scholar 

  7. S. Mathew, P.S. Mukerjee, K.P. Vijayakumar, Optical and surface properties of spray- pyrolysed CdS thin films. Thin Solid Films 254, 278–284 (1995)

    Article  CAS  Google Scholar 

  8. X.L. Tong, D.S. Jiang, Y. Li, Z.M. Liu, M.Z. Luo, Femtosecond pulsed laser deposition of CdS thin films onto quartz substrates. Phys. Status Solidi A 203, 1992–1998 (2006)

    Article  CAS  Google Scholar 

  9. P. Boieriu, R. Sporken, Y. Xin, N.D. Browning, S. Sivamamthani, J. Electron. Mater. 29, 718–722 (2000)

    Google Scholar 

  10. B.R. Sankapal, R.S. Mane, C.D. Lokhande, Deposition of CdS thin films by the successive ionic layer adsorption and reaction (SILAR) method. Mater. Res. Bull. 35, 177–184 (2000)

    Article  CAS  Google Scholar 

  11. D. Patidar, R. Sharma, N. Jain, T.P. Sharma, N.S. Saxena, Optical properties of CdS sintered film. Bull. Mater. Sci. 29, 21–24 (2006)

    Article  CAS  Google Scholar 

  12. M.U. Rehman, A.K.S. Aqili, M. Shafique, Z. Ali, A. Maqsood, A. Kazmi, Properties of silver-doped CdS thin films prepared by closed space sublimation (CSS) techniques. Mater. Sci. Lett. 22, 127–129 (2003)

    Article  Google Scholar 

  13. I. Mártil de la Plaza, G. González-Díaz, F. Sánchez-Quesada, M. Rodríguez-Vidal, Structural and optical properties of r.f.-sputtered CdS thin films. Thin Solid Films 120, 31–36 (1984)

  14. M. Tsuji, T. Aramoto, H. Ohyama, T. Hibino, K. Omura, Characterization of CdS thin- film in high efficient CdS/CdTe solar cells. Jpn. J. Appl. Phys. 39, 3902–3906 (2000)

    Google Scholar 

  15. O. Vigil-Galán, J. Vidal-Larramendi, A. Escamilla-Esquivel, G. Contreras-Puente, F. Cruz-Gandarilla, G. Arriaga-Mejía, M. Chavarría-Castañeda, M. Tufiño-Velázquez, Physical properties of CdS thin films grown by pulsed laser ablation on conducting substrates: effect of the thermal treatment. Phys. Status Solidi A 203, 2018–2023 (2006)

    Article  Google Scholar 

  16. S.A. Mahmoud, A.A. Ibrahim, A.S. Riad, Physical properties of thermal coating CdS thin films using a modified evaporation source. Thin Solid Films 372, 144–148 (2000)

    Article  CAS  Google Scholar 

  17. X. Mathew, J.P. Enriquez, A. Romeo, A.N. Tiwari, CdTe/CdS solar cells on flexible substrates. Sol. Energy 77, 831–838 (2004)

    Article  CAS  Google Scholar 

  18. J.-H. Lee, Structural and optical properties of CdS thin films on organic substrates for flexible solar cell applications. J. Electroceramics 17, 1103–1108 (2006)

    Article  CAS  Google Scholar 

  19. J.-H. Lee, Influence of substrates on the structural and optical properties of chemically deposited CdS films. Thin Solid Films 515, 6089–6093 (2007)

    Article  CAS  Google Scholar 

  20. B.-S. Moon, J.-H. Lee, H. Jung, Comparative studies of the properties of CdS films deposited on different substrates by R.F. sputtering. Thin Solid Films 511–512, 299–303 (2006)

  21. K.P. Acharya, J.R. Skuza, R.A. Lukaszew, C. Liyanage, B. Ulrich, CdS thin films formed on flexible plastic substrates by pulsed-laser deposition. J. Phys. Condens. Matter 19, 196221 (2007)

    Article  Google Scholar 

  22. F.-J. Haug, T. Söderström, M. Python, V. Terrazzoni-Daudrix, X. Niquille, C. Ballif, Development of micromorph tandem solar cells on flexible low-cost plastic substrates. Solar Energy Mater. Solar Cells 93, 884–887 (2009)

    Google Scholar 

  23. J.K. Rath, M. Brinza, Y. Liu, A. Borreman, R.E.I. Schropp, Fabrication of thin film silicon solar cells on plastic substrate by very high frequency PECVD. Solar Energy Mater. Solar Cells 94, 1534–1541 (2010)

    Google Scholar 

  24. M.G. Faraj, K. Ibrahim, A. Salhin, Investigation of CIGS solar cells on polyethylene terephthalate substrates. Int. J. Polym. Mater. 60, 817–824 (2011)

    Google Scholar 

  25. E. Carsalade, A. Bernès, C. Lacabanne, S. Perraud, M. Lafourcade, M. Savignac, Transitions/relaxations in polyester adhesive/PET system. J. Thermal Anal. Calorim. 101, 849–857 (2010)

    Google Scholar 

  26. K.A. Sierros, D.A. Banerjee, N.J. Morris, D.R. Cairns, I. Kortidis, G. Kiriakidis, Mechanical properties of ZnO thin films deposited on polyester substrates used in flexible device applications. Thin Solid Films 519, 325–330 (2010)

    Google Scholar 

  27. M.-C. Choi, Y. Kim, C.-S. Ha, Polymers for flexible displays: from material selection to device applications. Prog. Polym. Sci. 33, 581–630 (2008)

  28. K.S. Ramaiah, R.D. Pilkington, A.E. Hill, R.D. Tomlinsonand, A.K. Bhatnagar, Structural and optical investigations on CdS thin films grown by chemical bath technique. Mater. Chem. Phys. 68, 22–30 (2001)

    Article  CAS  Google Scholar 

  29. S. Gupta, D. Patidar, M. Baboo, K. Sharma, N.S. Saxena, Investigation of Al Schottky junction on n-type CdS film deposited on polymer substrate. Front. Optoelectron. China 3, 321–327 (2010)

    Article  Google Scholar 

  30. Q. Zhou, Z. Ji, B.B. Hu, C. Chen, L. Zhao, C. Wang, Low resistivity transparent conducting CdO thin films deposited by DC reactive magnetron sputtering at room temperature. Mater. Lett. 61, 531–534 (2007)

    Article  CAS  Google Scholar 

  31. C. Guillén, J. Herrero, Comparison study of ITO thin films deposited by sputtering at room temperature onto polymer and glass substrates. Thin Solid Films 480–481, 129–132 (2005)

    Google Scholar 

  32. A.N. Banerjee, C.K. Ghosh, K.K. Chattopadhyay, H. Minoura, A.K. Sarkar, A. Akiba, A. Kamiya, T. Endo, Low-temperature deposition of ZnO thin films on PET and glass substrates by DC-sputtering technique. Thin Solid Films 496, 112–116 (2006)

    Article  CAS  Google Scholar 

  33. J. Tauc, Amorphous and Liquid Semiconductors (Plenum Press, New York, 1974)

    Book  Google Scholar 

  34. S.M. Sze, Physics of Semiconductor Devices, 2nd edn. (Wiley-Interscience, New York, 1981)

    Google Scholar 

  35. U. Pal, R. Silva-González, G. Martinez-Montes, M. Gracia-Jiménez, M.A. Vidal, Sh. Torres, Optical characterization of vacuum evaporated cadmium sulfide films. Thin Solid Films 305, 345–350 (1997)

    Google Scholar 

Download references

Acknowledgments

This project was supported by the Nano-Optoelectronic Research Laboratory (NOR) of the School of Physics, Universiti Sains Malaysia (USM) under Grant No. 305/PFIZIK/613321. M. G. Faraj wishes to thank the Ministry of Higher Education of the Kurdistan Regional Government/Iraq and the University of Koya/Iraq for awarding him a scholarship to pursue his PhD abroad.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. G. Faraj.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Faraj, M.G., Ibrahim, K. Comparison of cadmium sulfide thin films deposited on glass and polyethylene terephthalate substrates with thermal evaporation for solar cell applications. J Mater Sci: Mater Electron 23, 1219–1223 (2012). https://doi.org/10.1007/s10854-011-0576-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-011-0576-6

Keywords

Navigation