Abstract
The transient hot-wire technique is widely used for measurements of the thermal conductivity of most fluids. However, for some particular liquids such as concentrated nitric acid solutions or similar nitric mixtures, for which the thermal properties are important for industrial or security applications, this technique can be difficult to use, which is essentially due to incompatibility between measurement probe materials and highly electrically conducting and corrosive liquids. Moreover, the possible highly energetic (explosive) character of these liquids requires minimum volume liquid samples, and safety measurement devices and processes. It is the purpose of this paper to report on a new patented instrument, based on tantalum short-hot-wire probe technology, which responds to the above requirements and allows safe automated thermal-conductivity measurements of concentrated acid nitric solutions and similar nitric mixtures for liquid samples less than 2 cm3, with uncertainties better than 5%.
Similar content being viewed by others
References
Healy J.J., de Groot J.J., Kestin J. (1976). Physica 82C: 392
Beirao S.G.S., Ramires M.L.V., Dix M., Nieto de Castro C.A. (2006). Int. J. Thermophys. 27: 1018
Nagasaka Y., Nagashima A. (1981). J. Phys. E: Sci. Instrum. 14: 1435
Yamasue E., Susa M., Fukuyama H., Nagata K. (2002). J. Cryst. Growth 234: 121
Zhang X., Fujii M. (2000). Int. J. Thermophys. 21: 71
Fukuyama H., Yoshimura T., Yasuda H., Ohta H. (2006). Int. J. Thermophys. 27: 1760
Alloush A., Gosney W.B., Wakeham W.A. (1982). Int. J. Thermophys. 3: 225
Kawamata K., Nagasaka Y., Nagashima A. (1988). Int. J. Thermophys. 9: 317
Ramires M.L.V., Fareleira J.M.N.A., Nieto de Castro C.A., Dix M., Wakeham W.A. (1993). Int. J. Thermophys. 14: 6
Ramires M.L.V., Nieto de Castro C.A., Fareleira J.M.N., Wakeham W.A. (1994). J. Chem. Eng. Data 39: 186
Perkins R.A., Ramires M.L.V., Nieto de Castro C.A. (2000). J. Res. Natl. Inst. Stand. Technol. 105: 255
Davis P.S., Theeuwes F., Bearman R.J., Gordon R.P. (1971). J. Chem. Phys. 55: 4776
Van Der Held E.F.M., Van Drunen F.G. (1949). Physica XV 10: 865
Bleazard J.G., Teja A.S. (1995). J. Chem. Eng. Data 40: 732
DiGuilio R.M., Lee R.J., Jeter S.M., Teja A.S. (1990). ASHRAE Trans. 96: 702
Griesinger A., Spindler K., Hahne E. (1997). Heat Mass Transfer 32: 419
Griesinger A., Heidemann W., Hahne E. (1999). Int. Comm. Heat Mass Transfer 26: 451
D. Roy, CEA Report (1997)
Cardonne S.M., Kumar P., Michaluk C.A., Schwartz H.D. (1995) . Int. J. Refract. Met. Hard Mater. 13: 187
Milosevic N.D., Vukovic G.S., Pavicic D.Z., Maglic K.D. (1999). Int. J. Thermophys. 20: 1129
Cardarelli F., Taxil P., Savall A. (1996). Int. J. Refract. Met. Hard Mater. 14: 365
Vermilyea D.A. (1953). Acta Metall. 1: 282
Thevenot G., Saillard J., J.-P. Maye, J.-Ph. Garnier, EP 1724572 A1, European Patent Office (2006)
Wakeham W.A., Zalaf M. (1987). Fluid Phase Equilib. 36: 183
Watanabe H. (1997). Int. J. Thermophys. 18: 2
Liang X.-G. (1996). Meas. Sci. Technol. 6: 467
Knibbe P.G. (1986). Int. J. Heat Mass Transfer 29: 463
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Garnier, J.P., Maye, J.P., Saillard, J. et al. A New Transient Hot-Wire Instrument for Measuring the Thermal Conductivity of Electrically Conducting and Highly Corrosive Liquids using Small Samples. Int J Thermophys 29, 468–482 (2008). https://doi.org/10.1007/s10765-008-0388-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10765-008-0388-y