Skip to main content
SpringerLink
Log in

Protection of stainless steel by the electrodeposition of polyaniline/poly(o-phenylenediamine) composite layers

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

Three polyaniline (PANI)/poly(o-phenylenediamine) (PoPD) mixtures have been electrochemically deposited on a stainless steel surface from an acidic solution. Electrocopolymerization was favorable at high molar ratios of aniline to o-phenylenediamine, and the resulting copolymer is a random type. Two bilayers, PoPD/PANI and PANI/PoPD, were prepared by successive electrodeposition, during which different multiphase structures were obtained. The presence of PoPD with PANI in the copolymer or multilayer structures enhances the passivation of the SS. The bi-layer coating in which a PANI layer lies under the PoPD produced the best passive oxide on the SS. The resistance to pitting increases with the coating order as follows: PANI < copolymer ≪ PANI/PoPD < PoPD < PoPD/PANI.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Okamoto G, Shibata T (1978) In: Frankenthal RP, Kruger J (eds) Passivity of metals. The Electrochemical Society monograph series. Electrochemical Society, Princeton, p 646

    Google Scholar 

  2. DeBerry DW (1985) J Electrochem Soc 132:1022–1026

    Article  CAS  Google Scholar 

  3. D’Elia LF, Ortiz RL, Marquez OP, Marquez J, Martinez Y (2001) J Electrochem Soc 148:C297–300

    Article  Google Scholar 

  4. Gasparac R, Martin CR (2001) J Electrochem Soc 148:B138–145

    Article  CAS  Google Scholar 

  5. Kilmartin PA, Trier L, Wright GA (2002) Synth Met 131:99–109

    Article  CAS  Google Scholar 

  6. Galkowski M, Malik MA, Kulesza PJ, Bala H, Miecznikowski K, Wlodarezyk R, Adamezyk L, Chojak M (2003) J Electrochem Soc 150:B249–253

    Article  CAS  Google Scholar 

  7. Hermas AA, Nakayama M, Ogura K (2005) Electrochim Acta 50:2001–2007

    Article  CAS  Google Scholar 

  8. Hermas AA, Nakayama M, Ogura K (2005) Electrochim Acta 50:3640–3647

    Article  CAS  Google Scholar 

  9. Hermas AA, Wu ZX, Nakayama M, Ogura K (2006) J Electrochem Soc 153:B199–204

    Article  CAS  Google Scholar 

  10. Hermas AA (2008) Prog Org Coat 61:95–102

    Article  CAS  Google Scholar 

  11. Abdel Salam M, Al-Juaid SS, Qusti AH, Hermas AA (2011) Synth Met 161:153–157

    Article  Google Scholar 

  12. Ganash AA, Al-Nowaiser FM, Al-Thabaiti SA, Hermas AA (2011) Prog Org Coat 72:480–485

    Article  CAS  Google Scholar 

  13. Kraljic M, Mandic Z (2003) Duic Lj. Corros Sci 45:181–198

    Article  Google Scholar 

  14. Spinks GM, Dominis AJ, Wallace GG, Tallman DE (2002) J Solid State Electrochem 6:85–91

    Article  CAS  Google Scholar 

  15. Malika MA, Galkowski MT, Bala H, Grzybowskab B, Kulesza PJ (1999) Electrochim. Acta 44:2157–2163

    Google Scholar 

  16. Herrasti P, Recio FJ, Ocon P, Fatas E (2005) Prog Org Coat 54(2005):285–291

    Article  CAS  Google Scholar 

  17. Pereira da Silva JE, Cordoba de Torresi SI, Torresi RM (2007) Prog Org Coat 58:33–39

    Article  CAS  Google Scholar 

  18. Yagan A, Pekmez NO, Yildiz A (2007) Prog Org Coat 59:297–303

    Article  CAS  Google Scholar 

  19. Narayanasamy B, Rajendran S (2010) Prog Org Coat 67:246–254

    Article  CAS  Google Scholar 

  20. Wei Y, Hariharan R, Patel SA (1990) Macromolecules 23:758–764

    Article  CAS  Google Scholar 

  21. Sathiyanarayanan S, Karpakam V, Kamaraj K, Muthukrishnan S, Venkatachari G (2010) Surf Coat Tech 204:1426–1431

    Article  CAS  Google Scholar 

  22. Gomes EC, Oliveira MAS (2011) Surf Coat Tech 205:2857–2864

    Article  CAS  Google Scholar 

  23. Kamaraj K, Karpakam V, Sathiyanarayanan S, Venkatachari G (2010) Mater Chem Phys 122:123–128

    Article  CAS  Google Scholar 

  24. Cotareloa MA, Huertab F, Quijadab C, Casesb F, Vázqueza JL (2005) Synth Met 148:81–88

    Article  Google Scholar 

  25. IUPAC “Glossary of Basic Terms in Polymer Science” (1996) Pure Appl Chem 68:2287

    Google Scholar 

  26. Painter PC, Coleman MM (1997) Funds Polymer Sci. CRC, Boca Raton, p 14

  27. Chen W-C, Wen T-C, Gopalan A (2001) J Electrochem Soc 148:E427–34

    Article  CAS  Google Scholar 

  28. Pekmez-Özcicek N, Pekmez K, Holze R, Yildiz A (2003) J Appl Polym Sci 89:862–868

    Google Scholar 

  29. Malinauskas A, Bron M, Holze R (1998) Synth Met 92:127–137

    Article  CAS  Google Scholar 

  30. Li XG, Wang HY, Huang MR (2007) Macromolecules 40:1489–1496

    Article  CAS  Google Scholar 

  31. Chen Y, Kang ET, Neoh KG (2002) Appl Surf Sci 185:267–276

    Article  CAS  Google Scholar 

  32. Moraes SR, Huerta-Vilca D, Motheo AJ (2004) Eur Polym J 40:2033–2041

    Article  CAS  Google Scholar 

  33. Chiba K, Ohsaka T, Ohnuki Y, Oyama N (1987) J Electroanal Chem Interfacial Electrochem 219:117–122

    Article  CAS  Google Scholar 

  34. Bilal S, Holze R (2007) Electrochim Acta 52:5346–5356

    Article  CAS  Google Scholar 

  35. Hermas AA (2008) Corros Sci 50:2498–2505

    Article  CAS  Google Scholar 

  36. Sivakkumar SR, Saraswathi R (2004) J Appl Electrochem 34:1147–1152

    Article  CAS  Google Scholar 

  37. Fahlman M, Jasty S, Epstein AJ (1997) Synth Met 85:1323–1326

    Article  CAS  Google Scholar 

  38. Salaneck WR, Liedberg B, Inganas O, Erlandsson R, Lundstrom I, MacDiarmid AG, Halpern M, Somasiri NLD (1985) Mol Cryst Liq Cryst 121:191–194

    Article  CAS  Google Scholar 

  39. Ohsaka T, Watanabe T, Kitamura F, Oyama N, Tokuda K (1991) J Chem Soc, Chem Commun, 1072–1073

  40. Lacroix J-C, Camalet J-L, Aeiyach S, Chane-Ching KI, Petitjean J, Chauveau E, Lacaze P-C (2000) J Electroanal Chem 481:76–81

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia

    A. A. Ganash, F. M. Al-Nowaiser, S. A. Al-Thabaiti & A. A. Hermas

  2. Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt

    A. A. Hermas

Authors
  1. A. A. Ganash
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. M. Al-Nowaiser
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. A. Al-Thabaiti
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Hermas
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Hermas.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ganash, A.A., Al-Nowaiser, F.M., Al-Thabaiti, S.A. et al. Protection of stainless steel by the electrodeposition of polyaniline/poly(o-phenylenediamine) composite layers. J Solid State Electrochem 17, 849–860 (2013). https://doi.org/10.1007/s10008-012-1940-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-012-1940-z

Keywords

Search

Navigation