Abstract
The interaction of six macrocyclic polyethers with 1, 3, 5-trinitrobenzene has been studied by spectroscopic methods. The association constants have been evaluated by1HMR chemical shift method. There is evidence that major contribution to the interaction isvia n andπ electrons. The donor strengths of the polyethers have been evaluated.
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Jayathirtha, Y., Krishnan, V. Molecular complexes of macrocyclic polyethers with 1, 3, 5-trinitrobenzene. Proc. Indian Acad. Sci. 86, 465–470 (1977). https://doi.org/10.1007/BF03046878
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DOI: https://doi.org/10.1007/BF03046878