Summary
The bulk polymerization of methyl methacrylate (MMA) with 1,2-disubstituted tetraphenylethanes, tetraphenylsuccinodinitrile (TPSN), tetra(p-methoxyphenyl)succinodinitrile (TMPSN), and pentaphenylethane (PPE), was investigated. These compounds were found to serve as thermal iniferters to induce living radical polymerization via a mechanism close to the model proposed previously (see Eq. 2). However, the living nature was not so high, because undesirable side reactions occurred. The oligomer with molecular weight of 2500 was isolated from the reaction mixture of MMA with TPSN, which was found to cause further polymerization of MMA. From the polymerization of styrene (St) with the polymers obtained by these iniferters, the block copolymers were produced.
Similar content being viewed by others
References
M. Gomberg, J. Am. Chem. Soc.,22, 757 (1900).
M. Gomberg, Chem. Rev.,1, 91 (1924).
G. V. Schulz and G. Wittig, Naturwissenschaften,27, 387 (1939).
G. V. Schulz, Z. Elektrochem.,47, 265 (1941).
G. V. Schulz, Kunststoffe,33, 224 (1943).
E. Borsig, M. Lazár and M. Čapla, Makromol. Chem.,105, 212 (1967).
E. Borsig, M. Lazár and M. Čapla, Collect. Czech. Chem. Commun.,33, 4264 (1968).
A. Błedzki and D. Braun, Makromol. Chem.,182, 1047 (1981).
A. Błedzki, H. Balard and D. Braun, ibid.182, 1057 (1981).
H. Balard, A. Błedzki and D. Braun, ibid182, 1063 (1981).
A. Błedzki, D. Braun and K. Titzschkau, ibid184, 745 (1983).
T. Otsu and M. Yoshida, Makromol. Chem., Rapid Commun.,3, 127 (1982).
T. Otsu, M. Yoshida and T. Tazaki, ibid3, 133 (1982).
T. Otsu, M. Yoshida and A. Kuriyama, Polym. Bull.,7, 45 (1982).
T. Otsu and M. Yoshida, ibid7, 197 (1982).
T. Otsu, A. Kuriyama and M. Yoshida, Kobunshi Ronbunshu,40, 583 (1983).
T. Otsu and A. Kuriyama, Polym. Bull.,11, 135 (1984).
T. Otsu and A. Kuriyama, J. Macromol. Sci.-Chem.,A21, 961 (1984).
A. Kuriyama and T. Otsu, Polym. J.,16, 511 (1984).
T. Otsu and A. Kuriyama, ibid17, 97 (1985).
T. Otsu, K. Yamashita and K. Tsuda, Macromolecules,19, 287 (1986).
T. Otsu and T. Tazaki, Polym. Bull.,16, 277 (1986).
T. Otsu, A. Matsumoto and T. Tazaki, Mem. Fac. Eng., Osaka City Univ.,27, 137 (1986).
K. Auwers and V. Mayers, Chem. Ber.,22, 1227 (1889).
G. Wittig and W. Hopf, ibid65, 760 (1932).
A. Bistrzycki, J. Paulus and R. Perrin, ibid44, 2596 (1911).
A. Löwenbein and R. F. Gagarin, ibid58, 2643 (1925).
W. E. Bachmann, J. Am. Chem. Soc.,55, 2135 (1933).
E. Cohn-Ginsberg, T. G. Fox and H. F. Mason, Polymer,3, 97 (1962).
T. Tazaki and T. Otsu, Polym. Bull., in press.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Otsu, T., Matsumoto, A. & Tazaki, T. Radical polymerization of methyl methacrylate with some 1,2-disubstituted tetraphenylethanes as thermal iniferters. Polymer Bulletin 17, 323–330 (1987). https://doi.org/10.1007/BF00955715
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00955715