Conclusions
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1.
The reactions of BCl3 in CCHCl3 with MNO3 (M=K, Rb, Cs, (CH3)4N, (C2H5)4N, (C4H9)4N) proceed slowly at 20° and are accompanied by decomposition of the NO −3 ion. The degree of decomposition increases with increase in the size of the cation.
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2.
It was established that M[Cl3BONO2] and M[B(ONO2)4] are formed as intermediate compounds; one of the intermediate products (C2H5)4N[B(ONO2)4] was isolated and identified. The final solid reaction products contain MBCl4.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2359–2361, October, 1975.
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Titova, K.V., Rosolovskii, V.Y. Reaction of nitrates of monovalent cations with BCl3 . Russ Chem Bull 24, 2246–2248 (1975). https://doi.org/10.1007/BF00929774
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DOI: https://doi.org/10.1007/BF00929774