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Colloidal Crystals of Spheres and Cubes in Real and Reciprocal Space

  • Book
  • © 2015

Overview

  • Nominated as an outstanding PhD thesis by the University of Utrecht, Netherlands
  • Provides a detailed overview of particle synthesis and colloidal crystal preparation
  • Describes the thorough characterization of these 3D colloidal crystals through experimental techniques in real and reciprocal space
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (9 chapters)

Keywords

About this book

This thesis presents an in-depth study on the effect of colloidal particle shape and formation mechanism on self-organization and the final crystal symmetries that can be achieved. It demonstrates how state-of-the-art X-ray diffraction techniques can be used to produce detailed characterizations of colloidal crystal structures prepared using different self-assembly techniques, and how smart systems can be used to investigate defect formation and diffusion in-situ. One of the most remarkable phenomena exhibited by concentrated suspensions of colloidal particles is the spontaneous self-organization into structures with long-range spatial and/or orientational orders. The study also reveals the subtle structural variations that arise by changing the particle shape from spherical to that of a rounded cube. In particular, the roundness of the cube corners, when combined with the self-organization pathway, convective assembly or sedimentation, was shown to influence the final crystal symmetries.

Authors and Affiliations

  • Van’t Hoff Laboratory for Physical and Colloid Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, The Netherlands

    Janne-Mieke Meijer

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