Abstract
crystal films of manganese oxide of composite materials were investigated by the method of X-ray photoelectronic spectroscopy in the fresh and spent state. The efficiency of modification was confirmed whereby on the surface of substrates of the carbonate type forms a thin-film crystalline structure of MnO2. We have found the relationship between the structure of crystalline film and substrate nature, which affects technical characteristics of the sorbent–catalyst. The mechanism of catalytic oxidation of manganese compounds in aqueous solutions using synthesized sorbents–catalysts was defined.
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DBN B.2.5-74:2914. Vodopostachannya. Zovnisni merezhi ta spourudy. Osnovni polozhennya proektuvannya. Vved. 01.01.2014. (Water supply. External Networks and Facilities. Basic Statutes of Designing. Introduced on Jan. 1, 2014.
MU 21.1.4.2898-11. Sanitarno-epidemiologicheskie issledovaniya (ispytaniya) materialov, reagenov i oborudovaniya, ispolzuemykh dla vodoochistki i vodopodgotovki. Vved. 12.07, 2011. (Sanitary-Epidemiological Research (Tests) of Materials, Reagents and Equipment Used for Water Purification and Water Treatment. Introduced on July 12, 2011.
GOST P 51641-2000. Materialy Filtriruyushchie zernistye. Obshchie tehncheskie usloviya. Vved 12.07.2011. (Materials Filtering Granulated. General Technical Conditions. Introduced on July 12, 2011.
Berezovskii, P. V., Ekonomicheskaya otsenka vtorichnykh mineralnykh resursov (Economic Assessment of Secondary Mineral Resources), SPb: SPGGI (TU), 2006.
Mossur, P.M. and Negoda, S.V., Gornyi. Inform.-Analit. Byul., 2006 pp. 299–307.
Mamchenko, A.V., Yakupova, I.V., Savchenko, O.A., Chernova, N.N., and Kii, N.N., Energotekhnologii i Resoursosberezheniye, 2012, no. 4, pp. 66–70.
Goncharuk, V.V., Mamchenko O.V., Kii, N.N., Chernova, L.G., and Misochka, I.V., Patent of Ukraine 84108, IPC BOIJ 20/02, C02F 1/64, publ. Sep. 10, 2008, Byul. no. 17.
Mamchenko, A.V., Kii, N.N., Chernova, L.G., J. Water Chem. and Technol., 2008, vol. 30, no. 4, pp. 191–197.
Mamchenko, A.V., Yakupova, I.V., Savchenko, O.A., and Chernova, N.N., Rus. J. Appl. Chem., 2012, vol. 85, no. 10, pp. 1501–1508.
Hassa, G., Fizika tonkikh plenok: v 3kh t., Moscow: Izd-vo Kniga po trebovaniyu, 2012, vol. 3.
Nesbitt, H.W. and Banerjee, D., Amer. Mineral., 1998, vol. 83, pp. 305–315.
Kanaparthi, R., Chen, L., Chen, F., Liu, Y., Wang, Z., and Han, Y., Catal Today., 2008, vol. 131, pp. 477–482.
Hussain, S., Amade, R., Jover, E., and Bertran, E., Sci. World J., 2013, vol. 8, pp. 1–8, Access mode: http://www.Researchgate.net/publication/25935463_Water_Plasma_Functionalized_CNTsMnO2_Composites_for_Super-capacitors.
Biesinger, M.C. and Payne, B., Appl. Surface Sci., 2011, vol. 257, pp. 2717–2730.
Kowalik, M., Zalecli, R., and Kolodsiejczyk, A., Actaphysicapolonica, 2010, vol. 117, pp. 277–266.
Fetisov, A.B., Kozhina, G.A., Fetisov, V.B., and Pastukhov, E.A., Zhurn. Prikl. Spektroskopii, 2011. vol. 78, no. 2, pp. 261–266.
Alekhin, A. P,,Grigal, I.P., Gudkova, S.A., et al., Tr. MFTI, 2011, vol. 3, no. 3, pp. 22–29.
Stadnichenko, A.I., Koshcheev, S.V., and Boronin, A.I., Vest. Mosk. Un-ta, series 2, 2007, vol. 48, no. 6, pp. 418–426.
Vogle, E.M., Ahmed, K.Z., and Hornung, B., IEEE Trans. Electron Devices, 1998, vol. 45, pp. 1350–1355.
Kulakov, V.V., Soshnikov, E.V., and Chaikovskii, G.P., Obezzhelezivanie i Demanganatsiya podzemnykh vodz: Ucheb. Pos. (Deironization and Demanganization of Underground Waters: Manual. Khabarovsk: DVGUPS, 1998.
Skolubovich, Yu.L., Voitov, Skolubovich, A.Yu., Vest. Tomsk. State. Architect.-stroit. Un-ta., 2013, no. 4, pp. 243–251.
Mamchenko, A.V., Savchenko, O.A., Chernova, N.N., and Yakupova, I.V., J. Water Chem. and Technol., 2012, vol. 34, no. 4, pp. 169–175.
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Original Russian Text © I.V. Yakupova, A.V. Mamchenko, O.V. Savchenko, N.N. Chernova, I.M. Kosygina, 2016, published in Khimiya i Tekhnologiya Vody, 2016, Vol. 38, No. 3, pp. 245–259.
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Yakupova, I.V., Mamchenko, A.V., Savchenko, O.V. et al. Investigation of the structure of the surface of sorbents–catalysts modified with MnO2 by the method of X-ray photoelectronic spectroscopy. J. Water Chem. Technol. 38, 134–142 (2016). https://doi.org/10.3103/S1063455X16030036
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DOI: https://doi.org/10.3103/S1063455X16030036