Abstract
The article has studied the impact of various physicochemical factors (the concentration of H2O2: alcohol ratio, the presence of oxygen, of Fe(III) ions, etc.) on the consumption and buildup of H2O2 in oxidation of aliphatic alcohols in aqueous solutions under the effect of UV light (200–360 nm). Based on the obtained data the kinetic model of generating H2O2 has been proposed in the processes being considered.
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Original Russian Text © A.A. Nosonovich, N.M. Soboleva, V.V. Goncharuk, 2011, published in Khimiya i Tekhnologiya Vody, 2011, Vol. 33, No. 5, pp. 465–476.
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Nosonovich, A.A., Soboleva, N.M. & Goncharuk, V.V. The generation of hydrogen peroxide in the processes of oxidation of aliphatic alcohols in the UV/H2O2 system. J. Water Chem. Technol. 33, 273–280 (2011). https://doi.org/10.3103/S1063455X11050018
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DOI: https://doi.org/10.3103/S1063455X11050018