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Synthesis of Pt-TM(transition metals) Catalysts and Their Hydrogenation Ability of Methyl Acrylate

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Abstract

We have prepared a number of Pt-TM(transition metals) alloys with various TM elements and evaluated their catalytic abilities by means of hydrogenation of methyl acrylate. High catalytic activities are obtained when the crystalline structures are similar, i.e., fcc structure, indicating that the crystal structure of a catalyst plays an important role in hydrogenation of methyl acrylate. Furthermore, for a certain TM element, i.e., Mo, the catalytic activity is found to surpass that of Pt metal.

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Authors and Affiliations

  1. Department of Materials Science and Technology, Tokyo University of Science, 2641 Yamazaki, 278-8510, Noda, Chiba, Japan

    Amari Miki, Okada Satoshi, Nishio Keishi, Shibata Hirobumi & Tamura Ryuji

  2. Fuel Cell Materials Center, National Institute for Materials Science, 1-2-1 Sengen, 305-0047, Tsukuba, Ibaraki, Japan

    Demura Masahiko

  3. Deparment of applied chemistry, Tokyo University of Science. Yamaguchi, 1-1-1 Daigakudori, 756-0884, Sanyo-Onoda, Yamaguchi, Japan

    Kineri Tohru

  4. Department of science and engineering, Tokyo University of Science, 2641 Yamazaki, 278-8510, Noda, Chiba, Japan

    Gunji Takahiro

Authors
  1. Amari Miki
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  2. Okada Satoshi
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  3. Demura Masahiko
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  4. Nishio Keishi
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  5. Shibata Hirobumi
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  6. Kineri Tohru
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  7. Gunji Takahiro
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  8. Tamura Ryuji
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Miki, A., Satoshi, O., Masahiko, D. et al. Synthesis of Pt-TM(transition metals) Catalysts and Their Hydrogenation Ability of Methyl Acrylate. MRS Online Proceedings Library 1217, 834 (2009). https://doi.org/10.1557/PROC-1217-Y08-34

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  • DOI: https://doi.org/10.1557/PROC-1217-Y08-34

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