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Cycloadducts of methyl hydroxyalkynoates and DBU: Transformation into tethered furan-2(5H)-one and caprolactam structures

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Abstract

Cycloadducts of 1,8-diazabicyclo[5.4.0]undec-7-ene and methyl 4-hydroxyalk-2-ynoates, octahydro-5H,9H-[1,3]oxazolo[2′,3′: 2,3]pyrimido[1,2-a]azepines, in the presence of potassium hydroxide in aqueous ethanol were converted to structures in which furan-2(5H)-one and caprolactam rings are linked to each other through an aminopropane tether.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    B. A. Trofimov, O. A. Shemyakina, A. V. Stepanov, O. G. Volostnykh & A. G. Mal’kina

Authors
  1. B. A. Trofimov
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  2. O. A. Shemyakina
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  3. A. V. Stepanov
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  4. O. G. Volostnykh
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  5. A. G. Mal’kina
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Corresponding author

Correspondence to B. A. Trofimov.

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Original Russian Text © B.A. Trofimov, O.A. Shemyakina, A.V. Stepanov, O.G. Volostnykh, A.G. Mal’kina, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 12, pp. 1857–1859.

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Trofimov, B.A., Shemyakina, O.A., Stepanov, A.V. et al. Cycloadducts of methyl hydroxyalkynoates and DBU: Transformation into tethered furan-2(5H)-one and caprolactam structures. Russ J Org Chem 53, 1893–1895 (2017). https://doi.org/10.1134/S1070428017120211

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  • DOI: https://doi.org/10.1134/S1070428017120211

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