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Electrochemical deposition of molybdenum oxide into films of poly(3,4-ethylenedioxythiophene) conducting polymer on glassy carbon substrates

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Electrochemical deposition of molybdenum oxides from molybdate-containing solutions onto glassy carbon electrodes and the same electrodes coated with a film of poly(3,4-ethylenedioxythiophene) conducting polymer was studied. The morphology of the deposited molybdenum oxides was examined by scanning electron microscopy. The method of X-ray photoelectron spectroscopy was used to determine the state of molybdenum in surface molybdenum oxides and a conclusion was made that the oxide MoO2 is mostly present.

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References

  1. Chernova, N.A., Roppolo, M., and Dillon, A.C., J. Mater. Chem., 2009, vol. 19, pp. 2526–2552.

    Article  CAS  Google Scholar 

  2. He, T. and Yao, J., J. Photochem. Photobiol. C, 2003, vol. 4, pp. 125–143.

    Article  CAS  Google Scholar 

  3. Guerfi, A., Paynter, R.W., and Dao, L.H., J. Electrochem. Soc., 1995, vol. 142, pp. 3457–3464.

    Article  CAS  Google Scholar 

  4. Yang, Y.A., Cao, Y.W., Loo, B.H., and Yao, J.N., J. Phys. Chem. B, 1998, vol. 102, pp. 9392–9396.

    Article  CAS  Google Scholar 

  5. Lee, M.-J., Kim, S.I., Lee, C.B., et al., Adv. Funct. Mater., 2009, vol. 19, pp. 1587–1593.

    Article  CAS  Google Scholar 

  6. Saji, V.S. and Lee, C.W., ChemSusChem., 2012, vol. 5, pp. 1146–1161.

    Article  CAS  Google Scholar 

  7. Hu, B., Mai, L., Chen, W., and Yang, F., ACS Nano, 2009, vol. 3, pp. 478–482.

    Article  CAS  Google Scholar 

  8. Ivanova, T., Szekeres, A., Gartner, M., et al., Electrochim. Acta, 2001, vol. 46, pp. 2215–2219.

    Article  CAS  Google Scholar 

  9. Ivanova, T., Gesheva, K.A., and Szekeres, A., J. Solid State Electrochem., 2002, vol. 7, pp. 21–24.

    Article  CAS  Google Scholar 

  10. Jankowski, A.F. and Schrawyer, L.R., Thin Solid Films, 1990, vols. 193–194, pp. 61–71.

    Article  Google Scholar 

  11. Lee, S.-H., Seong, M.J., Tracy, E., et al., Solid State Ionics, 2002, vol. 147, pp. 129–133.

    Article  CAS  Google Scholar 

  12. Martínez, H.M., Torres, J., Rodríguez-García, M.E., et al., Physica B, 2012, vol. 407, pp. 3199–3202.

    Article  Google Scholar 

  13. Sinkeviciute, D., Batrusaitis, J., and Dukstiene, N., J. Solid State Electrochem., 2011, vol. 15, pp. 711–723.

    Article  CAS  Google Scholar 

  14. Yao, D.D., Ou, J.Z., Latham, K., et al., Cryst. Growth Design, 2012, vol. 12, pp. 1865–1870.

    Article  CAS  Google Scholar 

  15. Gad-Allah, A.G. and Abd El-Rahman, H.A., J. Appl. Electrochem., 1988, vol. 18, pp. 312–313.

    Article  CAS  Google Scholar 

  16. Kuznetsov, V.V., Pavlov, M.R., Zimakov, D.I., et al., Russ. J. Electrochem., 2004, vol. 40, no. 7, pp. 711–715.

    Article  CAS  Google Scholar 

  17. Machida, K. and Enyo, M., J. Electrochem. Soc., 1990, vol. 137, pp. 1169–1175.

    Article  CAS  Google Scholar 

  18. Ivanova, N.D., Ivanov, S.V., Boldyrev, E.I., et al., Zashch. Met., 2006, vol. 42, pp. 388–392.

    Google Scholar 

  19. Podlaha, E.J. and Landolt, D.L., J. Electrochem. Soc., 1996, vol. 143, pp. 885–892.

    Article  CAS  Google Scholar 

  20. Podlaha, E.J. and Landolt, D.J., J. Electrochem. Soc., 1996, vol. 143, pp. 893–899.

    Article  CAS  Google Scholar 

  21. Podlaha, E.J. and Landolt, D.J., J. Electrochem. Soc., 1997, vol. 144, pp. 1672–1680.

    Article  CAS  Google Scholar 

  22. Rajak Sye., Ghosh, S.K., Sastry, P.U., et al., Surf. Coat. Technol., 2015, vol. 261, pp. 15–20.

    Article  Google Scholar 

  23. McEvoy, T.M. and Stevenson, K.J., Langmuir, 2003, vol. 19, pp. 4316–4326.

    Article  CAS  Google Scholar 

  24. McEvoy, T.M. and Stevenson, K.J., Anal. Chim. Acta, 2003, vol. 496, pp. 39–51.

    Article  CAS  Google Scholar 

  25. McEvoy, T.M. and Stevenson, K.J., J. Mater. Res., 2004, vol. 19, pp. 429–438.

    Article  CAS  Google Scholar 

  26. Patil, R.S., Uplane, M.D., and Patil, P.S., Appl. Surf. Sci., 2006, vol. 252, pp. 8050–8056.

    Article  CAS  Google Scholar 

  27. Gómez, E., Pellicer, E., and Vallés, E., J. Electroanal. Chem., 2005, vol. 580, pp. 238–244.

    Article  Google Scholar 

  28. Gacicuta, M., Boutaleb, Y., Cattin, L., et al., Phys. Status Solidi A, 2010, vol. 207, pp. 1905–1911.

    Article  Google Scholar 

  29. Sinyavskii, A., Yarlykov, M.M., Kudryavtsev, V.N., and Anufriev, N.G., Gal’vanotekh. Obrab. Poverkhn., 2000, vol. 8, pp. 15–22.

    CAS  Google Scholar 

  30. Samartsev, A.G. and Levitina, E.I., Zh. Fiz. Khim., 1958, vol. 32, pp. 1023–1028.

    CAS  Google Scholar 

  31. Vas’ko, A.T. and Kovach, S.K., Elektrokhimiya tugoplavkikh metallov (Electrochemistry of Refractory Metals), Kiev: Tekhnika, 1983.

    Google Scholar 

  32. Quintana, A., Varea, A., Guerrero, M., et al., Electrochim. Acta, 2015, vol. 173, pp. 705–714.

    Article  CAS  Google Scholar 

  33. Spitsyn, V.I. and Martynenko, L.I., Neorganicheskaya khimiya (Inorganic Chemistry), Moscow: Vysshaya shkola, 1994, vol. 2.

  34. Pope, M.T., Heteropolyanion and Isopolyoxo Metallates, New York: Springer, 1983.

    Book  Google Scholar 

  35. Bard, A.J., Parsons, R., and Jordan, J., Standard Potentials in Aqueous Solutions, IUPAC, New York: Marcel Dekker, 1985.

    Google Scholar 

  36. Tourillon, G., Polythiophene and Its Derivatives, Handbook of Conducting Polymers, Skotheim, T.A., Ed., New York: Marcel Dekker, 1986, pp. 293–350.

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Correspondence to D. V. Zhuzhel’skii.

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Original Russian Text © D.V. Zhuzhel’skii, K.D. Yalda, V.N. Spiridonov, S.N. Eliseeva, V.V. Kondratiev, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 8, pp. 1002−1010.

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Zhuzhel’skii, D.V., Yalda, K.D., Spiridonov, V.N. et al. Electrochemical deposition of molybdenum oxide into films of poly(3,4-ethylenedioxythiophene) conducting polymer on glassy carbon substrates. Russ J Appl Chem 89, 1252–1260 (2016). https://doi.org/10.1134/S1070427216080061

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  • DOI: https://doi.org/10.1134/S1070427216080061

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