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Coordination polymers of rare-earth elements with 2-aminoterephthalic acid

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Abstract

Coordination polymers of REEs with 2-aminoterephthalic acid [Ln2(C8H5NO4)3(H2O)5] n · 2nH2O (Ln = Eu, Gd, or Tb) and [Y2(C8H5NO4)3(H2O)4] n · 4nH2O were prepared by hydrothermal synthesis. Studies of the thermal behavior of these coordination polymers have shown that the removal of the solvate and the coordinated water molecules occurs at heating to 250°C and dehydratation products are stable up to 400°C. Detailed studies of the magnetic behavior of Eu, Gd, and Tb polymers were performed.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    S. Petrosyants, Zh. Dobrokhotova, A. Ilyukhin, A. Gavrikov, N. Efimov & V. Novotortsev

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  1. S. Petrosyants
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  2. Zh. Dobrokhotova
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  3. A. Ilyukhin
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  4. A. Gavrikov
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  5. N. Efimov
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  6. V. Novotortsev
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Corresponding author

Correspondence to S. Petrosyants.

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† Deceased.

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Petrosyants, S., Dobrokhotova, Z., Ilyukhin, A. et al. Coordination polymers of rare-earth elements with 2-aminoterephthalic acid. Russ J Coord Chem 43, 770–779 (2017). https://doi.org/10.1134/S1070328417110069

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  • DOI: https://doi.org/10.1134/S1070328417110069

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