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Synthesis and Structure of a New Cobalt Complex with Nitrogen Heterocycles

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Abstract

A new complex, {[Co(HDPDP)2(H2O)4]⋅2SO4}n, was prepared under hydrothermal condition based on 4,4'-(2,5-dimethoxy-1,4-phenylene) dipyridine ligands (DPDP) and cobalt cations. On this basis, we characterized it by IR spectra, TG analysis, and PXRD. Interestingly, the complex is a multi-dimensional structure formed by hydrogen bonding.

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ACKNOWLEDGMENTS

This work was supported by quality engineering of Anqing Normal University in 2018 (2018aqnujyxm052), AnHui provincial quality engineering project in 2019 (2019jyxm0291) and AnHui natural science foundation youth project (1908085QB49).

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Authors and Affiliations

  1. AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials, Key Laboratory of Functional Coordination Compounds of Anhui Higher Education Institutes, Anqing Normal University, 246133, Anqing, China

    C. L. Zhang & J. L. Qian

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  1. C. L. Zhang
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  2. J. L. Qian
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Correspondence to C. L. Zhang.

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Zhang, C.L., Qian, J.L. Synthesis and Structure of a New Cobalt Complex with Nitrogen Heterocycles. Crystallogr. Rep. 66, 1290–1294 (2021). https://doi.org/10.1134/S1063774521070245

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