Abstract
A comprehensive approach to the determination of the elemental composition of oils (including those with a viscosity of 5000 mm2/s) is proposed. It ensures the determination of the most elements present in oils using two versions of sample preparation, autoclave decomposition of oil samples and extraction preconcentration of elements from oil into an aqueous solution on rotating coiled columns (RCCs). The application of RCCs in the elemental analysis of oil ensures the preconcentration of a number of trace elements from oil (including rare-earth elements) and the determination of their concentrations at a level of ng/kg. The preconcentration factor of trace elements from oil using an RCC depends on the volume of oil sample pumped through a constant volume of the stationary phase (acid solution) retained in the column and on the speciation of elements in the oil.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ahmad, H., Tsafe, A.I., Zuru, A.A., Shehu, R.A., Atiku, F.A., and Itodo, A.U., Int. J. Nat. Appl. Sci., 2010, vol. 6, no. 1, p. 10.
Kalinin, E.P., Vestnik, 2009, no. 1, p. 6.
Sanchez, R., Todoli, J.L., Lienemann, Ch.-Ph., and Mermet, J.-M., Spectrochim. Acta, Part B, 2013, vol. 88, p. 104.
Sedykh, E.M., Bannykh, L.N., Korobeinik, G.S., and Starshinova, N.P., Zavod. Lab., Diagn. Mater., 2010, vol. 76, no. 4, p. 4.
Yasnygina, T.A., Rasskazov, S.V., Markova, M.E., Zharov, A.E., Malykh, Yu.M., Saranina, E.V., and Fefelov, N.N., Tikhookean. Geol., 2015, vol. 34, no. 2, p. 32.
Akinlua, A., Sigedle, A., Buthelezi, T., and Fadipe, O.A., Marine Petrol. Geol., 2015, vol. 59, p. 286.
Gottikh, R.P., Vinokurov, S.F., and Pisotskii, B.I., Dokl. Earth Sci., 2009, vol. 425, no. 1, p. 325.
Gottikh, R.P., Pisotskii, B.I., and Plotnikova, I.N., Georesursy, 2012, vol. 47, no. 5, p. 24.
Maryutina, T.A. and Soin, A.V., Anal. Chem., 2009, vol. 81, p. 5896.
Soin, A., Maryutina, T., Musina, N., and Soin, An., Int. J. Spectrosc., 2012, 174697. doi 10.1155/ 2012/174697
Conway, W.D., Countercurrent Chromatography: Apparatus, Theory, and Applications, New York: VCH, 1990.
Sukhanov, A.A. and Petrova, Yu.E., Neftegazov. Geol., Teor. Pract., 2008, vol. 3, no. 2. http://www.ngtp.ru/rub/9/23_2008.pdf. Cited May 26, 2016.
Maryutina, T.A., Soin, A.V., and Katasonova, O.N., J. Chromatogr. A, 2009, vol. 1216, p. 4232.
Yashchenko, I.G., Izv. Tomsk. Politekh. Univ., 2012, vol. 321, no. 1, p. 105.
Garanin, V.K., Kudryavtsev, G.P., Posukhova, T.V., and Sergeeva, N.E., Elektronno-zondovye metody izucheniya mineralov (Electron Probe Methods to Study Minerals), Moscow: Mosk. Gos. Univ., 1987.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.A. Maryutina, E.Yu. Savonina, O.N. Katasonova, 2016, published in Zhurnal Analiticheskoi Khimii, 2016, Vol. 71, No. 11, pp. 1183–1187.
Rights and permissions
About this article
Cite this article
Maryutina, T.A., Savonina, E.Y. & Katasonova, O.N. A combined method of sample preparation for the determination of the total element composition of oils. J Anal Chem 71, 1126–1130 (2016). https://doi.org/10.1134/S1061934816110101
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934816110101