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Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

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Abstract

A complex oxide Ba5In1.9Y0.1Al2ZrO13 with hexagonal perovskite structure (a = 5.971(4) Å, с = 24.012(1) Å) is prepared for the first time. The phase is found to dissociative-absorb water from gas phase, the degree of hydration being as high as 0.39 mol Н2О. It was found by using IR-spectroscopy that protons are present therein as energetically nonequivalent ОН–-groups involved in hydrogen bonds of diverse strength. Isovalent yttrium-doping of the Ba5In2Al2ZrO13 phase is shown not to lead to any valuable change in the oxygen-ion-conductivity as compared with the Ba5In2.1Al2Zr0.9O12.95 acceptor doping that allows increasing the oxygen-ion-conductivity by a factor of 1.3. Both types of doping lead to increase in the proton conductivity and, as a corollary to this, an increase in the proton concentration. For these phases the degree of hydration depends on the cell parameters, hence, is determined by space availability for ОН–-groups in the barium coordination. Proton transport dominates in the Ba5In2Al2ZrO13, Ba5In2.1Al2Zr0.9O12.95, and Ba5In1.9Y0.1Al2ZrO13 phases below 600оС in humid atmosphere (pH2О = 1.92 × 10–2 atm).

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Funding

This study is supported by the joined grant of the Russian Scientific Foundation and the Government of Sverdlovskaya oblast no. 22-23-20003, https://rscf.ru/en/project/22-23-20003/.

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Authors and Affiliations

  1. Ural Federal University named after the First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia

    R. D. Andreev, I. A. Anokhina, D. V. Korona, A. R. Gilev & I. E. Animitsa

  2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, 620137, Yekaterinburg, Russia

    R. D. Andreev, I. A. Anokhina & D. V. Korona

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  1. R. D. Andreev
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  2. I. A. Anokhina
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  3. D. V. Korona
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  4. A. R. Gilev
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  5. I. E. Animitsa
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Correspondence to I. E. Animitsa.

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Translated by Yu. Pleskov

Based on the materials of the 16th International Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, June 27–July 7, 2022.

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Andreev, R.D., Anokhina, I.A., Korona, D.V. et al. Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13. Russ J Electrochem 59, 190–203 (2023). https://doi.org/10.1134/S1023193523030035

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  • DOI: https://doi.org/10.1134/S1023193523030035

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