Abstract
In the present work, a shape-stable phase change material has been prepared by blending the polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene triblock copolymer and paraffin. Different mass fractions of block copolymer have been used to produce composites material. The structural, chemical and morphological analyses of composites have been done. Differential scanning calorimetry and thermogravimetric analysis results indicated that the addition of supporting material (block copolymer) improves the thermal stability without much affecting the phase transition temperature of paraffin. The paraffin leakage in composites is analyzed by mass loss over thermal cycles in an oven at 80°C and the best performance has been achieved for 20 wt% of block copolymer into the composite. The thermal reliability of this sample has been investigated after 100 thermal cycles. Overall inspection of results suggested that the prepared composite is the most appropriate shape-stable phase change material for thermal energy storage applications because of their acceptable energy storage capacity, good thermal stability and reliability, physical and chemical compatibility, low cost and easy synthesis process.
Similar content being viewed by others
REFERENCES
W. Su, J. Darkwa, and G. Kokogiannakis, Renewable Sustainable Energy Rev. 48, 373 (2015).
K. Pielichowska and K. Pielichowski, Prog. Mater. Sci. 65, 67 (2014).
Y. Tang, D. Su, X. Huang, G. Alva, L. Liu, and G. Fang, Appl. Energy 180, 116 (2016).
R. Rickert, R. Klein, and F. Schönberger, Materials 13, 3285 (2020).
M. Akgün, O. Aydın, and K. Kaygusuz, Energy Convers. Manage. 48, 669 (2007).
Y. Shi, M. Hu, Y. Xing, and Y. Li, Mater. Des. 185, 108219 (2020).
Y. Qu, S. Wang, D. Zhou, and Y. Tian, Renewable Energy 146, 2637 (2020).
V. Chalkia, N. Tachos, P. K. Pandis, A. Giannakas, M. K. Koukou, M. G. Vrachopoulos, and V. N. Stathopoulos, RSC Adv. 8, 27438 (2018).
D. Wu, B. Ni, Y. Liu, S. Chen, and H. Zhang, J. Mater. Chem. A 3, 9645 (2015).
S. Kim, H. Moon, and J. Kim, Thermochim. Acta 613, 9 (2015).
M. Mu, P. A. M. Basheer, W. Sha, Y. Bai, and T. McNally, Appl. Energy 162, 68 (2016).
R. Al-Shannaq, M. Farid, S. Al-Muhtaseb, and J. Kurdi, Sol. Energy Mater. Sol. Cells 132, 311 (2015).
Q. Huang, X. Li, G. Zhang, J. Deng, and C. Wang, Appl. Therm. Eng. 183, 116151 (2021).
S. M. Lai, and X. F. Wang, J. Appl. Polym. Sci. 134, 45475 (2017).
S. Song, J. Feng, and P. Wu, Macromol. Rapid Commun. 32, 1569 (2011).
M. Pantoja, P. Z. Jian, M. Cakmak, and K. A. Cavicchi, ACS Appl. Polym. Mater. 1, 414 (2019).
A. Sarı, C. Alkan, and C. Bilgin, Appl. Energy, 136, 217 (2014).
C. Alkan, K. Kaya, and A. Sarı, J. Polym. Environ. 17, 254 (2009).
Z. Liu, X. Lan, W. Bian, L. Liu, Q. Li, Y. Liu, and J. Leng, Composites, Part B 193, 108056 (2020).
H. Hu, Composites, Part B 195, 108094 (2020).
Q. Zhang, Y. Zhao, J. Feng, Sol. Energy Mater. Sol. Cells 118, 54 (2013).
W. Wu, W. Wu, and S. Wang, Appl. Energy 236, 10 (2019).
Q. Zhang, S. Song, J. Feng, and P. Wu, J. Mater. Chem. 22, 24776 (2012).
A. Khan, P. Saikia, R. Saxena, D. Rakshit, and S. Saha, Int. J. Energy Res. 44, 1567 (2020).
P. Chen, X. Gao, Y. Wang, T. Xu, Y. Fang, and Z. Zhang, Sol. Energy Mater. Sol. Cells, 149, 60 (2016).
S. Tang, Y. Xu, G. Su, J. Bao, and A. Zhang, RSC Adv. 8, 35429 (2018).
B. Xiang, Z. Yang, and J. Zhang, Polym. Adv. Technol. 32, 420 (2021).
I. Chriaa, A. Trigui, M. Karkri, I. Jedidi, M. Abdelmouleh, and C. Boudaya, Appl. Therm. Eng. 171, 115072 (2020).
Z. Zhang, N. Zhang, J. Peng, X. Fang, X. Gao, and Y. Fang, Appl. Energy 91, 426 (2012).
T. Wu, Y. Hu, H. Rong, and C. Wang, Energy 221, 119900 (2021).
S. Peng, A. Fuchs, and R. A. Wirtz, J. Appl. Polym. Sci. 93, 1240 (2004).
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Jaspreet Singh Aulakh, Deepika P. Joshi Development of Paraffin-Based Shape-Stable Phase Change Material for Thermal Energy Storage. Polym. Sci. Ser. A 64, 308–317 (2022). https://doi.org/10.1134/S0965545X22200056
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0965545X22200056