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Vanadium-Containing Heteropoly Acids of Keggin Structure as Precursors of CoPMoV Sulfide Catalysts for Hydroconversion of Dibenzothiophene and Naphthalene

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Abstract

Mixed PMoV heteropoly acids of Keggin structure, H3+xPVxMo12–xO40 (x = 1–3), were synthesized. Alumina-supported sulfide catalysts were prepared by the support impregnation with a solution of mixed heteropoly acids and Co citrate, followed by activation in an H2S stream. The physicochemical characteristics of the catalyst samples were determined, and their catalytic properties in dibenzothiophene hydrodesulfurization and naphthalene hydrogenation were studied. The catalytic system containing CoPVMo11 showed higher hydrogenating and hydrodesulfurizing activity at 300–320°С.

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Funding

The study was financially supported by the Russian Science Foundation, project no. 19-79-10016, https://rscf.ru/project/19-79-10016/.

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Authors and Affiliations

  1. Samara State Technical University, 443100, Samara, Russia

    V. V. Timoshkina, N. A. Vinogradov & A. A. Pimerzin

  2. Gibkin Russian State University of Oil and Gas (Natural Research University), 119991, Moscow, Russia

    N. A. Vinogradov, A. A. Pimerzin, A. V. Vutolkina & A. P. Glotov

  3. OOO Gazpromneft–Promyshlennye Innovatsii, 197350, St. Petersburg, Russia

    A. A. Pimerzin

  4. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    A. V. Vutolkina

Authors
  1. V. V. Timoshkina
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  2. N. A. Vinogradov
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  3. A. A. Pimerzin
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  4. A. V. Vutolkina
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Correspondence to V. V. Timoshkina.

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Timoshkina, V.V., Vinogradov, N.A., Pimerzin, A.A. et al. Vanadium-Containing Heteropoly Acids of Keggin Structure as Precursors of CoPMoV Sulfide Catalysts for Hydroconversion of Dibenzothiophene and Naphthalene. Pet. Chem. 62, 1343–1349 (2022). https://doi.org/10.1134/S0965544122110044

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