Abstract
Herein, we demonstrate for the first time the synthesis of copper tungstate (CuWO4) crystal by a facile polyacrylamide gel route. X-ray diffraction patterns reveal that the pure phase CuWO4 obtained by calcining xerogel at 900°C has the triclinic crystal structure. The component of prepared CuWO4 are further confirmed by the X-ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. Transmission electron microscope results demonstrate that the CuWO4 has high crystallinity. Ultraviolet-visible absorption spectra indicate that the samples have remarkable photoabsorption in the near-infrared region. Photoluminescence spectra show that the CuWO4 has an emission peak at 583 nm with excitation wavelength of 430 nm. The synthesized CuWO4 phosphors with attractive optical and photoluminescence properties have potential applications in photoelectric devices and lasers.
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REFERENCES
K. Aneesh, C. S. R. Vusa, and S. Berchmans, Sens. Actuators, B 253, 723 (2017).
A. C. Catto, T. Fiorido, E. L. S. Souza, et al., J. Alloys Compd. 748, 411 (2018).
L. Liang, H. Liu, Y. Tian, et al., Mater. Lett. 182, 302 (2016).
M. Thiruppathi, M. Vahini, P. Devendran, et al., J. Nanosci. Nanotechnol. 19, 7026 (2019).
S. M. Hosseinpour-Mashkani and A. Sobhani-Nasab, J. Mater. Sci.: Mater. Electron. 27, 7548 (2016).
W. Wang, L. W. Hu, J. B. Ge, et al., Chem. Mater. 26, 3721 (2014).
S. M. Pourmortazavi, M. Rahimi-Nasrabadi, M. Khalilian-Shalamzari, et al., J. Inorg. Organomet. Polym. 24, 333 (2014).
S. F. Wang, H. J. Gao, Y. Wang, et al., J. Electron. Mater. 49, 2450 (2020).
S. F. Wang, H. J. Gao, G. Z. Sun, et al., Opt. Mater. 99, 109562 (2020).
M. Denk, D. Kuhness, M. Wagner, et al., ACS Nano 8, 3947 (2014).
P. Raizada, S. Sharma, A. Kumar, et al., J. Environ. Chem. Eng. 8, 104230 (2020).
S. Dey, R. A. Ricciardo, H. L. Cuthbert, and P. M. Woodward, Inorg. Chem. 53, 4394 (2014).
Z. K. Wu, Z. Q. Zhao, G. Cheung, and R. M. Doughty, J. Electrochem. Soc. 166, H3014 (2019).
W. C. Ding, X. N. Wu, and Q. F. Lu, Mater. Lett. 253, 323 (2019).
F. Ahmadi, M. Rahimi-Nasrabadi, and M. Eghbali-Arani, J. Mater. Sci.: Mater. Electron. 28, 5244 (2017).
W. Zhang, J. J. Yin, F. Q. Min, et al., J. Alloys Compd. 690, 221 (2017).
Y. Gao, O. Zandi, and T. W. Hamann, J. Mater. Chem. A 4, 2826 (2016).
J. Ruiz-Fuertes, D. Errandonea, A. Segura, et al., High Press. Res. 28, 565 (2008).
E. L. S. Souza, J. C. Sczancoski, I. C. Nogueira, et al., Ultrason. Sonochem. 38, 256 (2017).
J. E. Yourey, and B. M. Bartlett, J. Mater. Chem. 21, 7651 (2011).
C. M. Tian, M. Jiang, D. Tang, et al., J. Mater. Chem. A 7, 11895 (2019).
M. Wen, S. Wang, R. Q. Jiang, et al., Biomater. Sci. 7, 4651 (2019).
G. Z. Sun, G. A. Sun, M. Zhong, S. F. Wang, X. T. Zu, and X. Xiang, Russ. J. Phys. Chem. A 90, 691 (2016).
S. F. Wang, H. J. Gao, J. Y. Li, et al., J. Phys. Chem. Solids 150, 109891 (2021).
J. Y. Li, S. F. Wang, G. A. Sun, et al., Mater. Today Chem. 19, 100390 (2021).
S. F. Wang, H. J. Gao, L. M. Fang, et al., Chem. Eng. J. Adv. 6, 100089 (2021).
S. F. Wang, G. Z. Sun, L. M. Fang, et al., Sci. Rep. 5, 12849 (2015).
A. S. Hammad, H. M. El-Bery, A. H. EL-Shazly, and M. F. Elkady, Int. J. Electrochem. Sci. 13, 362 (2018).
M. Eghbali-Arani, A. Sobhani-Nasabb, M. Rahimi-Nasrabadi, et al., Ultrason. Sonochem. 43, 120 (2018).
M. Thiruppathi, K. Selvakumar, M. Arunpandian, et al., Colloids Surf., A 563, 148 (2019).
A. Bhattacharjee and M. Ahmaruzzaman, RSC Adv. 6, 41348 (2016).
H. M. Dong, Y. H. Li, D. Gao, et al., J. Alloys Compd. 785, 660 (2019).
Z. Y. Lin, W. J. Li, and G. W. Yang, Appl. Catal. B 227, 35 (2018).
P. Nithya and C. Roumana, J. Mater. Sci.: Mater. Electron. 31, 9151 (2020).
P. Yadav and E. Sinha, Macromol. Symp. 388, 1900019 (2019).
O. Yu. Khyzhun, V. L. Bekenev, and Yu. M. Solonin, J. Alloys Compd. 480, 184 (2009).
M. V. Lalic, Z. S. Popovic, and F. R. Vukajlovic, Comput. Mater. Sci. 63, 163 (2012).
J. R. Fuertes, J. P. Porres, A. Segura, et al., J. Appl. Phys. 116, 103706 (2014).
ACKNOWLEDGMENTS
This work was supported by the Science and Technology Research Program of Chongqing Education Commission of China (KJQN202001225, KJZD-K202001202, KJQN201901), project (YB2020C0402, ZD2020A0401) supported by Chongqing Key Laboratory of Geological Environment Monitoring and Disaster Early-Warning in Three Gorges Reservoir Area, Chongqing Three Gorges University, the Talent introduction project (09826501, 09924601), the NSAF joint Foundation of China (U2030116), the Chongqing Natural Science Foundation (cstc2019jcyj-msxmX0310), project 2019DB02 supported by NPL, CAEP.
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Sun, G., Gao, Q., Tang, S. et al. Facile Synthesis, Optical and Photoluminescence Properties of Copper Tungstate Phosphors with Strong Near-Infrared Photoabsorption. Russ. J. Phys. Chem. 96, 1348–1355 (2022). https://doi.org/10.1134/S0036024422060097
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DOI: https://doi.org/10.1134/S0036024422060097