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Investigation of Electrochemical Characterization of the Protective Film Formed by the Novel Schiff’s Base on the Carbon Steel Surface in Acid Media: Temperature Effects and Thermodynamic Parameters

  • COLLOID CHEMISTRY AND ELECTROCHEMISTRY
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Abstract

Two Schiff bases containing different functional groups were synthesized. Their inhibition performance and adsorption behavior on carbon steel corrosion behavior in acidic media were investigated using electrochemical techniques at different concentrations and temperatures. Results showed that the inhibitors inhibited carbon steel corrosion in acid solution and indicated that the inhibition efficiencies were enhanced with an increase in concentration of inhibitor. Polarization studies showed that the inhibitors behave as mixed type of inhibitors. The adsorption of the inhibitors on a carbon steel surface obeys Langmuir’s adsorption isotherm. The values of activation energy and the thermodynamic parameters, such as Kads,\(\Delta G_{{{\text{ads}}}}^{^\circ }\),\(\Delta H_{{{\text{ads}}}}^{^\circ }\), and \(\Delta S_{{{\text{ads}}}}^{^\circ }\) were calculated and discussed. The surface adsorbed film was characterized by atomic force microscopy.

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REFERENCES

  1. R. A. Prabhu, T. V. Venkatesha, A. V. Shanbhag, G. M. Kulkarni, and R. G. Kalkhambkar, Corros. Sci. 50, 3356 (2008).

    Article  CAS  Google Scholar 

  2. L. A. Nnanna, I. O. Owate, O. C. Nwadiuko, N. D. Ekekwe, and W. J. Oji, Int. J. Mater. Chem. 3, 10 (2013).

    Google Scholar 

  3. E. A. Noor and A. H. Al-Moubaraki, Mater. Chem. Phys. 110, 145 (2008).

    Article  CAS  Google Scholar 

  4. N. A. Negm, F. M. Ghuiba, and S. M. Tawfik, Corros. Sci. 53, 3566 (2011).

    Article  CAS  Google Scholar 

  5. N. Soltani, M. Behpour, S. M. Ghoreishi, and H. Naeimi, Corros. Sci. 52, 1351 (2010).

    Article  CAS  Google Scholar 

  6. G. Quartarone, L. Ronchin, A. Vavasori, C. Tortato, and L. Bonaldo, Corros. Sci. 64, 82 (2012).

    Article  CAS  Google Scholar 

  7. K. Sayın, H. Jafari, and F. J. Mohsenifa, Taiwan Inst. Chem. Eng. 68, 43 (2016).

    Google Scholar 

  8. H. Keles, M. Keleş, I. Dehri, and O. Serindag, Mater. Chem. Phys. 112, 173 (2008).

    Article  CAS  Google Scholar 

  9. E. Bayol, K. Kayakırılmaz, and M. Erbil, Mater Chem. Phys. 104, 74 (2007).

    Article  CAS  Google Scholar 

  10. K. S. Jacob and G. Parameswaran, Corros. Sci. 52, 224 (2010).

    Article  Google Scholar 

  11. N. A. Negm, E. A. Badr, I. A. Aiad, M. F. Zaki, and M. M. Said, Corros. Sci. 65, 77 (2012).

    Article  CAS  Google Scholar 

  12. H. Ju, Zhen-Peng Kai, and Y. Li, Corros. Sci. 50, 865 (2008).

    Article  CAS  Google Scholar 

  13. M. Behpour, S. M. Ghoreishi, M. Salavati-Niasari, and B. Ebrahimi, Mater. Chem. Phys. 107, 153 (2008).

    Article  CAS  Google Scholar 

  14. I. Ahamad, R. Prasad, and M. A. Quraishi, Corros. Sci. 52, 933 (2010).

    Article  CAS  Google Scholar 

  15. R. Solmaz, E. Altunbas, and G. Kardas, Mater. Chem. Phys. 125, 796 (2011).

    Article  CAS  Google Scholar 

  16. M. Behpour, S. M. Ghoreishi, N. Mohammadi, N. Soltani, and M. Salavati-Niasari, Corros. Sci. 52, 4046 (2010).

    Article  CAS  Google Scholar 

  17. H. Abd El-Lateef, A. M. Abu-Dief, L. H. Abdel-Rahman, E. C. Sañudo, N. J. Aliaga, and N. J. Alcalde, Electroanal. Chem. 743, 120 (2015).

    Article  CAS  Google Scholar 

  18. S. E. Nataraja, T. V. Venkatesha, K. Manjunatha, B. Poojary, M. K. Pavithra, and H. C. Tandon, Corros. Sci. 53, 2651 (2011).

    Article  CAS  Google Scholar 

  19. K. C. Emregül, E. Düzgün, and O. Atakol, Corros. Sci. 48, 3243 (2006).

    Article  Google Scholar 

  20. C. M. Goulart, A. Esteves-Souza, C. A. Martinez-Huitle, C. J. F. Rodrigues, M. A. M. Maciel, and A. Echevarria, Corros. Sci. 67, 281 (2013).

    Article  CAS  Google Scholar 

  21. I. Danaee, O. Ghasemi, G. R. Rashed, M. Rashvand Avei, and M. H. Maddahy, J. Mol. Struct. 1035, 247 (2013).

    Article  CAS  Google Scholar 

  22. M. P. Desimone, G. Gordillo, and S. N. Simison, Corros. Sci. 53, 4033 (2011).

    Article  CAS  Google Scholar 

  23. M. A. Hegazy, A. M. Hasan, M. M. Emara, M. F. Bakr, and A. H. Youssef, Corros. Sci. 65, 67 (2012).

    Article  CAS  Google Scholar 

  24. N. F. Atta, A. M. Fekry, and H. M. Hassaneen, Int. J. Hydrogen Energy 36, 6462 (2011).

    Article  CAS  Google Scholar 

  25. H. Hamani, T. Douadi, D. Daoud, M. Al-Noaimi, R. A. Rikkouh, and S. Chafaa, J. Electroanal. Chem. 801, 425 (2017).

    Article  CAS  Google Scholar 

  26. B. S. Prathibha, H. P. Nagaswarupa, P. Kotteeswaran, and V. BheemaRaju, Mater. Today Proc. 4, 12245 (2017).

    Article  Google Scholar 

  27. R. Kumar, O. S. Yadav, and G. Singh, J. Mol. Liq. 237, 413 (2017).

    Article  CAS  Google Scholar 

  28. R. Kumar, H. Kimb, and G. Singh, J. Mol. Liq. 259, 199 (2018).

    Article  CAS  Google Scholar 

  29. N. O. Obi-Egbedi and I. B. Obot, Arabian J Chem. 6, 211 (2013).

    Article  CAS  Google Scholar 

  30. L. Herrag, B. Hammouti, S. Elkadiri, A. Aouniti, C. Jama, H. Vezin, and F. Bentiss, Corros. Sci. 52, 3042 (2010).

    Article  CAS  Google Scholar 

  31. A. Popova, Corros. Sci. 49, 2144 (2007).

    Article  CAS  Google Scholar 

  32. M. A. Hegazy, A. M. Badawi, S. S. Abd El Rehim, and W. M. Kamel, Corros. Sci. 69, 110 (2013).

    Article  CAS  Google Scholar 

  33. A. K. Singh, Sudhish K. Shuklaa, M. A. Quraishi, and E. E. Ebenso, J. Taiwan Inst. Chem. E 43, 463 (2012).

    Article  CAS  Google Scholar 

  34. H. Ashassi-Sorkhabi, B. Shaabani, and D. Seifzadeh, Appl. Surf. Sci. 239, 154 (2005).

    Article  CAS  Google Scholar 

  35. P. Muthukrıshnan, K. S. Kumar, B. Jeyaprabha, and P. Prakash, Metall. Mater. Trans. A 45, 4510 (2014).

    Article  Google Scholar 

  36. F. Mansfeld, J. Appl. Electrochem. 25, 187 (1995).

    Google Scholar 

  37. S. S. A. Rehim, O. A. Hazzazi, M. A. Amin, and K. F. Khaled, Corros. Sci. 50, 2258 (2008).

    Article  CAS  Google Scholar 

  38. R. Solmaz, G. Kardas, M. Culha, B. Yazıcı, and M. Erbil, Electrochim. Acta 53, 5941 (2008).

    Article  CAS  Google Scholar 

  39. S. Deng, X. Li, and H. Fu, Corros. Sci. 53, 760 (2011).

    Article  CAS  Google Scholar 

  40. H. Keles, Mater. Chem. Phys. 130, 1317 (2011).

    Article  CAS  Google Scholar 

  41. J. Aljourani, K. Raeissi, and M. A. Golozar, Corros. Sci. 51, 1836 (2009).

    Article  CAS  Google Scholar 

  42. M. Behpour, S. M. Ghoreishi, N. Soltani, and M. Salavati-Niasari, Corros. Sci. 51, 1073 (2009).

    Article  CAS  Google Scholar 

  43. G. Avcı, Colloids Surf., A 317, 730 (2008).

    Article  Google Scholar 

  44. M. Erbil, Chim. Acta Turc. 1, 59 (1988).

    Google Scholar 

  45. R. Solmaz, G. Kardas, B. Yazıcı, and M. Erbil, Colloid Surf., A 312, 7 (2008).

  46. H. Hamani, T. Douadi, D. Daouda, M. Al-Noaimi, R. A. Rikkouh, and S. J. Chafaa, Electroanal. Chem. 801, 438 (2017).

    Article  Google Scholar 

  47. A. M. Fekry and M. A. Ameer, Int. J. Hydrogen Energy 36, 11207 (2011).

    Article  CAS  Google Scholar 

  48. N. S. Ayati, S. Khandandel, M. Momeni, M. H. Moayed, A. Davoodi, and M. Rahimizadeh, Mater. Chem. Phys. 126, 873 (2011).

    Article  CAS  Google Scholar 

  49. F. Zhang, Y. Tang, Z. Cao, W. Jing, Z. Wu, and Y. Chen, Corros. Sci. 61, 1 (2012).

    Article  CAS  Google Scholar 

  50. M. Benabdellah, A. Tounsi, K. F. Khaled, and B. Hammouti, Arabian J. Chem. 4, 17 (2011).

    Article  CAS  Google Scholar 

  51. X. Li, S. Deng, and H. Fu, Corros. Sci. 55, 280 (2012).

    Article  CAS  Google Scholar 

  52. E. E. Oguzie, G. N. Onuoha, and A. I. Onuchukwu, Mater. Chem. Phys. 89, 305 (2005).

    Article  CAS  Google Scholar 

  53. M. S. Morad, Corros. Sci. 50, 436 (2008).

    Article  CAS  Google Scholar 

  54. R. Hasanov, M. Sadıkoğlu, and S. Bilgiç, Appl. Surf. Sci. 253, 3913 (2007).

    Article  CAS  Google Scholar 

  55. T. Ibrahim, H. Alayan, and Y. Al Mowaqet, Prog. Org. Coat. 75, 456 (2012).

    Article  CAS  Google Scholar 

  56. D. Seifzadeh, H. Basharnavaz, and A. Bezaatpour, Mater. Chem. Phys. 138, 794 (2013).

    Article  CAS  Google Scholar 

  57. M. M. Solomon, S. A. Umoren, I. I. Udosoro, and A. P. Udoh, Corros. Sci. 52, 1317 (2010).

    Article  CAS  Google Scholar 

  58. M. A. Amin, M. A. Ahmed, H. A. Arida, T. Arslan, M. Saracoglu, and F. Kandemirli, Corros. Sci. 53, 540 (2011).

    Article  CAS  Google Scholar 

  59. L. Li, Q. Qu, W. Bai, F. Yang, Y. Chen, S. Zhang, and Z. Ding, Corros. Sci. 59, 249 (2012).

    Article  Google Scholar 

  60. M. Bouklah, N. Benchat, B. Hammouti, A. Aouniti, and S. Kertit, Mater. Lett. 60, 1901 (2006).

    Article  CAS  Google Scholar 

  61. E. A. Flores, O. Olivares, N. V. Likhanova, M. A. Domínguez-Aguilar, N. Nava, D. Guzman-Lucero, and M. Corrales, Corros. Sci. 53, 3899 (2011).

    Article  CAS  Google Scholar 

  62. K. Tebbji, N. Faska, A. Tounsi, H. Oudda, M. Benkaddour, and B. Hammouti, Mater. Chem. Phys. 106, 260 (2007).

    Article  CAS  Google Scholar 

  63. E. Bayol, T. Gurten, A. A. Gurten, and M. Erbil, Mater. Chem. Phys. 112, 624 (2008).

    Article  CAS  Google Scholar 

  64. B G. E. Badr, Corros. Sci. 51, 2529 (2009).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

We are thankful to the Scientific Research Projects Unit (NUBAP, project no. FEB 2012/29) of Nigde University for their financial support during this study.

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  1. Niğde Ömer Halisdemir University, Faculty of Science and Arts, Department of Chemistry, 51240, Niğde, Turkey

    Duygu Ataş &  Emel Bayol

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  1. Duygu Ataş
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  2. Emel Bayol
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Correspondence to Emel Bayol.

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Duygu Ataş, Emel Bayol Investigation of Electrochemical Characterization of the Protective Film Formed by the Novel Schiff’s Base on the Carbon Steel Surface in Acid Media: Temperature Effects and Thermodynamic Parameters. Russ. J. Phys. Chem. 93, 359–368 (2019). https://doi.org/10.1134/S0036024419020080

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