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Kinetics of acid hydrolysis and reactivity of some antibacterial hydrophilic iron(II) imino-complexes

  • Chemical Kinetics and Catalysis
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Abstract

Kinetic study of acid hydrolysis of some hydrophilic Fe(II) Schiff base amino acid complexes with antibacterial properties was performed using spectrophotometry. The Schiff base ligands were derived from sodium 2-hydroxybenzaldehyde-5-sulfonate and glycine, L-alanine, L-leucine, L-isoleucine, DL-methionine, DL-serine, or L-phenylalanine. The reaction was studied in aqueous media under conditions of pseudo-first order kinetics. Moreover, the acid hydrolysis was studied at different temperatures and the activation parameters were calculated. The general rate equation was suggested as follows: rate = k obs [Complex], where k obs = k 2 [H+]. The evaluated rate constants and activation parameters are consistent with the hydrophilicity of the investigated complexes.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Sohag University, Sohag, Egypt

    Ali Mohamed Shaker, Lobna Abdel-Mohsen Ebaid Nassr, Mohamed Shaker Saied Adam & Ibrahim Mohamed Abdelhalim Mohamed

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  1. Ali Mohamed Shaker
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  2. Lobna Abdel-Mohsen Ebaid Nassr
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  3. Mohamed Shaker Saied Adam
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  4. Ibrahim Mohamed Abdelhalim Mohamed
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Correspondence to Ibrahim Mohamed Abdelhalim Mohamed.

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Shaker, A.M., Nassr, L.AM.E., Adam, M.S.S. et al. Kinetics of acid hydrolysis and reactivity of some antibacterial hydrophilic iron(II) imino-complexes. Russ. J. Phys. Chem. 89, 759–765 (2015). https://doi.org/10.1134/S0036024415050039

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  • DOI: https://doi.org/10.1134/S0036024415050039

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