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Palladium on ultradisperse diamond and activated carbon: the relation between structure and activity in hydrodechlorination

  • Chemical Kinetics and Catalysis
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Abstract

Ultradisperse diamond was studied as a promising carrier for Pd-containing hydrodechlorination catalysts. Transmission electron microscopy, temperature-programmed reduction, and the adsorption method were used to study catalysts on ultradisperse diamond and activated carbon and a commercial catalyst from Fluca. Catalyst activities in multiphase hydrodechlorination of chlorobenzenes were compared. The activity of Pd-containing catalysts on ultradisperse diamond was found to be several orders of magnitude higher than that of Pd catalysts on activated carbon.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Leninskie gory, Moscow, 119992, Russia

    S. A. Kachevskii, E. V. Golubina, E. S. Lokteva & V. V. Lunin

Authors
  1. S. A. Kachevskii
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  2. E. V. Golubina
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  3. E. S. Lokteva
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  4. V. V. Lunin
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Original Russian Text © S.A. Kachevskii, E.V. Golubina, E.S. Lokteva, V.V. Lunin, 2007, published in Zhurnal Fizicheskoi Khimii, 2007, Vol. 81, No. 6, pp. 998–1005.

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Kachevskii, S.A., Golubina, E.V., Lokteva, E.S. et al. Palladium on ultradisperse diamond and activated carbon: the relation between structure and activity in hydrodechlorination. Russ. J. Phys. Chem. 81, 866–873 (2007). https://doi.org/10.1134/S0036024407060064

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  • DOI: https://doi.org/10.1134/S0036024407060064

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