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Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide

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Abstract

The reaction of CuSO4⋅5H2O with glycine and 4-cyanopyridine in aqueous alkaline medium resulted in polymeric complex [Cu(ox)2(isn)2]·(CONH2)2]n (1) (where ox is oxalate, isn is isonicotinamide). Complex 1 has been studied by single crystal X-ray diffraction. Crystal structure reveals that complex 1 is a polymeric structure bridged by oxalate ions. Glycine has been oxidized to oxalate during the course of the reaction along with the in-situ hydrolysis of 4-cyanopyridine to isonicotinamide resulting in complex 1. Complex 1 was further characterized by molar conductance, UV-Vis and FT-IR spectroscopic techniques. The conversion of glycine to oxalate occurs spontaneously in aqueous solution under ambient conditions.

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ACKNOWLEDGMENTS

The authors thank SAIF, Gauhati University for single crystal X-ray diffraction data.

Funding

Linkon Bharali thanks DST for providing Inspire scholarship (Registration number: 201500053206).

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  1. Department of Chemistry, Cotton University, 781001, Guwahati, Assam, India

    Anshuman Gogoi &  Linkon Bharali

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  1. Anshuman Gogoi
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Correspondence to Anshuman Gogoi.

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Anshuman Gogoi, Linkon Bharali Conversion of Glycine to Oxalate in Presence of CuSO4⋅5H2O and Isonicotinamide. Russ. J. Inorg. Chem. 67, 608–615 (2022). https://doi.org/10.1134/S0036023622050072

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