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Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–

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Abstract

Currently, the chemistry of carbonyl derivatives of the closo-borate anions is actively developing. It is of great interest to obtain protonated complexes of these types of clusters for further directed functionalization. The aim of this study is to develop an approach to the preparation of the protonated complex of the monocarbonyl derivative [B10H9CO⋅Hfac]0. In the course of the work, the target complex has been obtained by protonation of the [B10H9CO]– anion with an excess of trifluoromethanesulfonic acid CF3SO3OH. In this reaction, the boron cluster is quantitatively protonated. When a base is added, the protonation process becomes reversible.

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REFERENCES

  1. X. Mu, J. C. Axtell, N. A. Bernier, et al., Chem. 5, 2461 (2019). https://doi.org/10.1016/j.chempr.2019.07.018

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  2. V. V. Avdeeva, E. A. Malinina, K. Y. Zhizhin, et al., Russ. J. Inorg. Chem. 65, 514 (2020). https://doi.org/10.1134/S0036023620040026

    Article  CAS  Google Scholar 

  3. F. Ali, N. S. Hosmane, and Y. Zhu, Molecules 25, 828 (2020). https://doi.org/10.3390/molecules25040828

    Article  CAS  PubMed Central  Google Scholar 

  4. T. Jelinek, B. Štibr, F. Mareš, et al., Polyhedron 6, 1737 (1987). https://doi.org/10.1016/S0277-5387(00)86544-4

    Article  CAS  Google Scholar 

  5. Z. Laila, O. Yazbeck, F. A. Ghaida, et al., J. Organomet. Chem. 910, 121132 (2020). https://doi.org/10.1016/j.jorganchem.2020.121132

    Article  CAS  Google Scholar 

  6. M. Y. Stogniy, S. A. Erokhina, I. B. Sivaev, et al., Phosphorus, Sulfur Silicon Relat. Elem. 194, 983 (2019). https://doi.org/10.1080/10426507.2019.1631312

    Article  CAS  Google Scholar 

  7. D. Naoufal, B. Bonnetot, and H. Mongeot, Appl. Organomet. Chem. 17, 244 (2003). https://doi.org/10.1002/aoc.424

    Article  CAS  Google Scholar 

  8. I. B. Sivaev, V. I. Bregadze, and S. Sjöberg, Collect. Czech. Chem. Commun. 67 (6), 679 (2002). https://doi.org/10.1135/cccc20020679

    Article  CAS  Google Scholar 

  9. A. Jankowiak, A. Balinski, J. E. Harvey, et al., J. Mater. Chem. C 1, 1144 (2013). https://doi.org/10.1039/c2tc00547f

    Article  CAS  Google Scholar 

  10. I. N. Klyukin, A. S. Kubasov, I. P. Limarev, et al., Polyhedron 101, 215 (2015). https://doi.org/10.1016/j.poly.2015.09.025

    Article  CAS  Google Scholar 

  11. S. G. Shore, E. J. M. Hamilton, A. N. Bridges, et al., Inorg. Chem. 42, 1175 (2003). https://doi.org/10.1021/ic020540s

    Article  CAS  PubMed  Google Scholar 

  12. V. K. Kochnev, V. V. Avdeeva, E. A. Malinina, et al., Russ. J. Inorg. Chem. 59, 706 (2014). https://doi.org/10.1134/S0036023614070079

    Article  CAS  Google Scholar 

  13. M. F. Hawthorne, I. J. Mavunkal, and C. B. Knobler, J. Am. Chem. Soc. 9, 4427 (1992).

    Article  Google Scholar 

  14. A. V. Ezhov, F. Y. Vyal’ba, I. N. Kluykin, et al., Macroheterocycles 10, 505 (2017). https://doi.org/10.6060/mhc171254z

    Article  CAS  Google Scholar 

  15. F. Abi-Ghaida, Z. Laila, and G. Ibrahim, Dalton Trans. 13087 (2014). https://doi.org/10.1039/c4dt00772g

  16. M. Diab, A. Mateo, J. Al Cheikh, et al., Dalton Trans. 49, 4685 (2020). https://doi.org/10.1039/C9DT04676C

    Article  CAS  PubMed  Google Scholar 

  17. I. N. Klyukin, A. S. Novikov, A. P. Zhdanov, et al., Mendeleev Commun. 30, 88 (2020). https://doi.org/10.1016/j.mencom.2020.01.029

    Article  CAS  Google Scholar 

  18. I. N. Klyukin, A. S. Novikov, A. P. Zhdanov, et al., Polyhedron 187, 114682 (2020). https://doi.org/10.1016/j.poly.2020.114682

    Article  CAS  Google Scholar 

  19. D. S. Wilbur, M. K. Chyan, D. K. Hamlin, et al., Bioconjug. Chem. 18, 1226 (2007). https://doi.org/10.1021/bc060345s

    Article  CAS  PubMed  Google Scholar 

  20. D. S. Wilbur, M. Chyan, H. Nakamae, et al., Bioconjug. Chem. 23, 409 (2012).

    Article  CAS  Google Scholar 

  21. K. Shelly, C. B. Knobler, and M. F. Hawthorne, Inorg. Chem. 31, 2889 (1992). https://doi.org/10.1021/ic00039a041

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

The studies were carried out using the equipment at the Center for Collective Use of the Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, which functions with the support of the State Assignment of the Kurnakov Institute RAS in the field of fundamental scientific research.

Funding

This work was supported by the Russian Science Foundation (grant no. 20-73-00326).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. N. Klyukin, A. V. Kolbunova, N. A. Selivanov, A. Yu. Bykov, A. P. Zhdanov, K. Yu. Zhizhin & N. T. Kuznetsov

  2. National Research University “Higher School of Economics”, 101000, Moscow, Russia

    A. V. Kolbunova

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  1. I. N. Klyukin
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  2. A. V. Kolbunova
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  3. N. A. Selivanov
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  4. A. Yu. Bykov
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  5. A. P. Zhdanov
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  6. K. Yu. Zhizhin
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  7. N. T. Kuznetsov
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Correspondence to I. N. Klyukin.

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Translated by V. Avdeeva

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Klyukin, I.N., Kolbunova, A.V., Selivanov, N.A. et al. Study of Protonation of the Monocarbonyl Derivative of the closo-Decaborate Anion [B10H9CO]–. Russ. J. Inorg. Chem. 66, 1798–1801 (2021). https://doi.org/10.1134/S003602362112007X

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  • DOI: https://doi.org/10.1134/S003602362112007X

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