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Conformation of diethylglyoxime in uranyl complexes

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Abstract

New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both cis- and trans-conformations. The structure of organic ligand C6H12N2O2 and binuclear complex (CN3H6)4[(UO2)2(C6H10N2O2)(CO3)(C2O4)2] ∙ H2O have been determined by X-ray diffraction.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. G. Beirakhov, I. M. Orlova, A. V. Rotov, E. G. Il’in, L. V. Goeva, M. D. Surazhskaya, A. V. Churakov & Yu. N. Mikhailov

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  1. A. G. Beirakhov
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  2. I. M. Orlova
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  3. A. V. Rotov
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  4. E. G. Il’in
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  5. L. V. Goeva
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  6. M. D. Surazhskaya
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  7. A. V. Churakov
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  8. Yu. N. Mikhailov
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Corresponding author

Correspondence to A. G. Beirakhov.

Additional information

Original Russian Text © A.G. Beirakhov, I.M. Orlova, A.V. Rotov, E.G. Il’in, L.V. Goeva, M.D. Surazhskaya, A.V. Churakov, Yu.N. Mikhailov, 2016, published in Zhurnal Neorganicheskoi Khimii, 2016, Vol. 61, No. 12, pp. 1583–1590.

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Beirakhov, A.G., Orlova, I.M., Rotov, A.V. et al. Conformation of diethylglyoxime in uranyl complexes. Russ. J. Inorg. Chem. 61, 1522–1529 (2016). https://doi.org/10.1134/S0036023616120032

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  • DOI: https://doi.org/10.1134/S0036023616120032

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