Abstract
Coordination compounds of samarium with acyldihydrazones of saturated dicarboxylic acids and 3-methyl-1-phenyl-4-formylpyrazol-5-one have been synthesized and studied. According to X-ray diffraction, the complexes are binuclear and contain nine-vertex coordination polyhedra linked by three hydrocarbon spacers. Solid samples manifest intense luminescence in the spectral region typical for samarium(III) complexes.
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References
F. Marchetti, C. Pettinari, and R. Pettinari, Coord. Chem. Rev. 249, 2909 (2005).
J. S. Casas, M. S. Garcia-Tasende, A. Sanchez, et al., Coord. Chem. Rev. 251, 1561 (2007).
M. A. Katkova, A. G. Vitukhnovskii, and M. N. Bochkarev, Usp. Khim. 74, 1193 (2005).
N. P. Kuz’mina and S. V. Eliseeva, Russ. J. Inorg. Chem. 51, 73 (2006).
D. Kepert, Inorganic Stereochemistry (Springer, Heidelberg, 1982; Mir, Moscow, 1985).
J. Li, Li Zhang, G. Liu, et al., Inorg. Chim. Acta 360, 3504 (2007).
X. Zhu, C. He, D. Dong, et al., Dalton Trans. 39, 10051 (2010).
V. F. Shul’gin, S. V. Abkhairova, O. V. Konnik, et al., Russ. J. Inorg. Chem. 57, 420 (2012).
S. B. Meshkova, Z. M. Topylova, V. F. Shul’gin, et al., Proceedings of the 1st International Conference on Luminescence of Lanthanides, Odessa (Ukraine), 2010, p. 92.
I. Ya. Kvitko and B. A. Porai-Koshits, Zh. Org. Khim. 34, 3005 (1964).
SMART (Control) and SAINT (Integration) Sofware, Version 5.0 Bruker, 1997).
G. M. Sheldrick, Acta Crystallogr., Sect. A 64, 112 (2008).
T. Boyle and A. M. Ottley, Chem. Rev. 108, 1896 (2008).
F. H. Allen, O. Kennard, D. G. Watson, et al., J. Chem. Soc., Perkin Trans. 2, No. 12, S1 (1987).
G. M. Larin, V. V. Minin, and V. F. Shul’gin, Usp. Khim. 77, 477 (2008).
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Original Russian Text © V.F. Shul’gin, Z.Z. Bekirova, O.V. Konnik, S.B. Meshkova, A.V. Kiriyak, G.G. Aleksandrov, I.L. Eremenko, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 5, pp. 606–611.
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Shul’gin, V.F., Bekirova, Z.Z., Konnik, O.V. et al. Coordination compounds of samarium with acyldihydrazones of saturated dicarboxylic acids and 3-methyl-1-phenyl-4-formylpyrazol-5-one. Russ. J. Inorg. Chem. 59, 441–445 (2014). https://doi.org/10.1134/S0036023614050167
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DOI: https://doi.org/10.1134/S0036023614050167