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Synthesis and structure of aminoguanidinium sulfite monohydrate

  • Physical Methods of Investigation
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Abstract

The reaction between sulfur(IV) oxide and an aqueous suspension of aminoguanidinium hydrocarbonate yields (CN4H7)2SO3 · H2O, an “onium” sulfite, which has been characterized by X-ray diffraction and IR spectroscopy and mass spectrometry. The structure of the salt is stabilized by numerous H-bonds, such as NH…O, OH…O, and NH…N. The incorporation of pyramidal SO 2−3 ions into the network of H-bonds is accompanied by the lowering of their symmetry in comparison with C 3v, thus complicating the IR spectra of the salt in the region where the vibrations of the anion appear.

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Authors and Affiliations

  1. Physicochemical Institute for Human and Environment Protection, Ministry of Education and Science and National Academy of Sciences of Ukraine, ul. Preobrazhenskaya 3, Odessa, 65026, Ukraine

    R. E. Khoma, V. O. Gelmboldt & L. V. Koroeva

  2. Mechnikov National University, ul. Dvoryanskaya 2, Odessa, 65025, Ukraine

    R. E. Khoma

  3. Odessa National Medical University, per. Valikhovskogo 2, Odessa, 65026, Ukraine

    V. O. Gelmboldt

  4. Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, Kharkiv, 61178, Ukraine

    V. N. Baumer & O. V. Shishkin

Authors
  1. R. E. Khoma
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  2. V. O. Gelmboldt
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  3. V. N. Baumer
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  4. O. V. Shishkin
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  5. L. V. Koroeva
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Correspondence to R. E. Khoma.

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Original Russian Text © R.E. Khoma, V.O. Gelmboldt, V.N. Baumer, O.V. Shishkin, L.V. Koroeva, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 7, pp. 950–954.

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Khoma, R.E., Gelmboldt, V.O., Baumer, V.N. et al. Synthesis and structure of aminoguanidinium sulfite monohydrate. Russ. J. Inorg. Chem. 58, 843–847 (2013). https://doi.org/10.1134/S0036023613070140

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  • DOI: https://doi.org/10.1134/S0036023613070140

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