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Chemical conversions of rhodium selenochloride Rh2Se9Cl6

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Abstract

Rhodium selenochloride Rh2Se9Cl6 (1) reacts with aqueous solutions of KCN and CsCl and 4-cyanopyridine (4-CNPy) to give complexes KCs2Rh(CN)6 (2) and RhCl3(4-CNPy)3 (3). According to X-ray diffraction data, 2 and 3 have mononuclear structures in which the rhodium atoms are in the oxidation state III and six-coordinate environment. Reactions 1 with CN-containing ligands lead to complete displacement of selenium-containing ligands from the rhodium coordination sphere.

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Authors and Affiliations

  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32-34, Kiev, 03680, Ukraine

    S. V. Volkov, O. G. Yanko, L. B. Khar’kova & Z. A. Fokina

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    Yu. V. Mironov, S. S. Yarovoi & A. I. Smolentsev

Authors
  1. S. V. Volkov
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  2. Yu. V. Mironov
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  3. S. S. Yarovoi
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  4. A. I. Smolentsev
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  5. O. G. Yanko
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  6. L. B. Khar’kova
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  7. Z. A. Fokina
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Additional information

Original Russian Text © S.V. Volkov, Yu.V. Mironov, S.S. Yarovoi, A.I. Smolentsev, O.G. Yanko, L.B. Khar’kova, Z.A. Fokina, 2011, published in Zhurnal Neorganicheskoi Khimii, 2011, Vol. 56, No. 3, pp. 424–427.

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Volkov, S.V., Mironov, Y.V., Yarovoi, S.S. et al. Chemical conversions of rhodium selenochloride Rh2Se9Cl6 . Russ. J. Inorg. Chem. 56, 383–386 (2011). https://doi.org/10.1134/S0036023611030260

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  • DOI: https://doi.org/10.1134/S0036023611030260

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