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The Influence of Chlorides on the Spectral Properties of Ion-Exchange Layers of Photo-Thermo-Refractive Glass

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Abstract

The influence of chlorides on the spectral properties of silver nanoparticles in ion-exchange layers of photo-thermo-refractive glass is studied. It is shown that silver particles in ion-exchange layers of photo-thermo-refractive glass without chlorides are formed only in the UV-irradiated region and the refractive index does not change under UR irradiation. It is found that UV irradiation and subsequent heat treatment lead to the growth of NaF crystals on Ag–AgCl/NaCl core–shell nanoparticles formed in UV-irradiated ion-exchange photo-thermo-refractive glass with chlorides. The difference between the refractive indices of the irradiated and non-irradiated regions of photo-thermo-refractive glass with chlorine reaches Δn = –3 × 10–3. The investigation results demonstrate the possibility of recording amplitude and amplitude–phase g-ratings in ion-exchange layers of chloride-free and chloride-doped photo-thermo-refractive glasses, res-pectively.

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ACKNOWLEDGMENTS

We are grateful to R.K. Nuryev for performing X-ray diffraction analysis.

Funding

This work was supported by the Russian Science Foundation (project no. 20-19-00559).

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Authors and Affiliations

  1. ITMO University, 199034, St. Petersburg, Russia

    D. V. Marasanov, Y. M. Sgibnev & N. V. Nikonorov

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  1. D. V. Marasanov
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Correspondence to D. V. Marasanov.

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Translated by M. Basieva

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Marasanov, D.V., Sgibnev, Y.M. & Nikonorov, N.V. The Influence of Chlorides on the Spectral Properties of Ion-Exchange Layers of Photo-Thermo-Refractive Glass. Opt. Spectrosc. 130, 402–408 (2022). https://doi.org/10.1134/S0030400X22070074

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