Abstract
Using the tellurium(IV) complex compounds as an example, we study the interrelation between the geometric structure and spectral luminescence properties. We find that, in the series of compounds of Te(IV), which are characterized by the island octahedral coordination of Te(IV) ions, the luminescence intensity depends on the degree of distortion of the Te(IV) coordination polyhedron, the Stokes shift, and the energy of the luminescence transition. We revealed that the considered series of Te(IV) compounds possess reversible thermochromic properties.
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Original Russian Text © T.V. Sedakova, A.G. Mirochnik, V.E. Karasev, 2011, published in Optika i Spektroskopiya, 2011, Vol. 110, No. 5, pp. 806–812.
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Sedakova, T.V., Mirochnik, A.G. & Karasev, V.E. Structure and luminescence properties of tellurium(IV) complex compounds. Opt. Spectrosc. 110, 755–761 (2011). https://doi.org/10.1134/S0030400X11030192
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DOI: https://doi.org/10.1134/S0030400X11030192