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Pd/Ga2O3–Al2O3 catalysts for the selective liquid-phase hydrogenation of acetylene to ethylene

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Abstract

The structure of Ga2O3–Al2O3 supports and Pd/Ga2O3–Al2O3 catalysts and the performance of these catalysts in liquid-phase acetylene hydrogenation have been investigated. The deposition of Ga(NO3)3 onto Al2O3 by impregnation followed by calcination of the impregnated support at 600°C yields γ-Ga2O3–Al2O3 solid solutions containing up to 50 wt % Ga2O3. X-ray diffraction characterization of model palladium catalysts and their temperature-programmed reduction with hydrogen have demonstrated that, while palladium in Pd/Ga2O3 is in the form of a Pd2Ga alloy, in the Pd/γ-Ga2O3–Al2O3 catalyst there is no direct interaction between PdО and Ga2O3 particles and palladium is in the monometallic state. The introduction of 10–20 wt % gallium oxide into Al2O3 lowers the activity of the supported palladium catalyst relative to that of the initial Pd/Al2O3 but increases the ethylene yield by enhancing the ethylene formation selectivity.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    T. N. Afonasenko, N. S. Smirnova, V. L. Temerev, N. N. Leont’eva, T. I. Gulyaeva & P. G. Tsyrul’nikov

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  1. T. N. Afonasenko
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  2. N. S. Smirnova
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  3. V. L. Temerev
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  4. N. N. Leont’eva
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  5. T. I. Gulyaeva
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  6. P. G. Tsyrul’nikov
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Correspondence to T. N. Afonasenko.

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Original Russian Text © T.N. Afonasenko, N.S. Smirnova, V.L. Temerev, N.N. Leont’eva, T.I. Gulyaeva, P.G. Tsyrul’nikov, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 4, pp. 493–500.

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Afonasenko, T.N., Smirnova, N.S., Temerev, V.L. et al. Pd/Ga2O3–Al2O3 catalysts for the selective liquid-phase hydrogenation of acetylene to ethylene. Kinet Catal 57, 490–496 (2016). https://doi.org/10.1134/S0023158416040017

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  • DOI: https://doi.org/10.1134/S0023158416040017

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