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Kinetic description of the hydrogenation of nitrobenzene and nitrosobenzene on skeletal nickel in aqueous solutions of propan-2-ol of different compositions

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Abstract

The kinetics of the hydrogenation of nitrosobenzene and nitrobenzene is simulated taking into account accompanying processes and specific features of the conversion of reactive groups. The constants of the hypothetical reaction steps are calculated. The influence of sodium hydroxide and acetic acid on the kinetic parameters of the reactions is discussed.

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Authors and Affiliations

  1. Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

    Yu. E. Romanenko, A. A. Merkin & O. V. Lefedova

Authors
  1. Yu. E. Romanenko
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  2. A. A. Merkin
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  3. O. V. Lefedova
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Corresponding authors

Correspondence to Yu. E. Romanenko or O. V. Lefedova.

Additional information

Original Russian Text © Yu.E. Romanenko, A.A. Merkin, O.V. Lefedova, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 2, pp. 206–212.

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Romanenko, Y.E., Merkin, A.A. & Lefedova, O.V. Kinetic description of the hydrogenation of nitrobenzene and nitrosobenzene on skeletal nickel in aqueous solutions of propan-2-ol of different compositions. Kinet Catal 57, 212–218 (2016). https://doi.org/10.1134/S0023158416020117

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  • DOI: https://doi.org/10.1134/S0023158416020117

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