Abstract
Cumyl hydroperoxide decomposition in chlorobenzene in the presence of magnesium, zinc, cadmium, or mercury 2-ethylhexanoate has been investigated. It has been established and kinetically proved that the decomposition reaction is preceded by the formation of a hydroperoxide-catalyst complex. Thermodynamic parameters of this complexation have been determined. The catalytic activity of the salts correlates with the ionization potentials of the metals.
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Original Russian Text © N.M. Nurullina, N.N. Batyrshin, Kh.E. Kharlampidi, 2013, published in Kinetika i Kataliz, 2013, Vol. 54, No. 6, pp. 702–706.
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Nurullina, N.M., Batyrshin, N.N. & Kharlampidi, K.E. Cumyl hydroperoxide decomposition under the action of group II metal compounds. Kinet Catal 54, 662–666 (2013). https://doi.org/10.1134/S0023158413060098
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DOI: https://doi.org/10.1134/S0023158413060098