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Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O

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Abstract

The diffusion of acetone vapor into a Na7H[Nb6O19] solution at pH 9.5 results in the crystallization of the Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O (1) complex characterized by X-ray diffraction. The sodium cation coordination to a triangular face of the anion enables the determination of anion protonation sites by blocking the disordering and the formation of strong hydrogen bonds between the anions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Abramov & M. N. Sokolov

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    P. A. Abramov & M. N. Sokolov

Authors
  1. P. A. Abramov
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  2. M. N. Sokolov
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Correspondence to P. A. Abramov.

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Original Russian Text © 2017 P. A. Abramov, M. N. Sokolov.

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Abramov, P.A., Sokolov, M.N. Crystal structure of Na10[{Na(H2O)H2Nb6O19}2(μ-H2O)2]·46H2O. J Struct Chem 58, 1411–1417 (2017). https://doi.org/10.1134/S0022476617070198

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  • DOI: https://doi.org/10.1134/S0022476617070198

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