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Structural characterization of a cadmium(II)-sulfato complex, [Cd(N,N′-diethyl thiourea)4(SO4)]

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Abstract

A cadmium(II) complex, tetrakis(N,N′-diethylthiourea)sulfatocadmium(II), [Cd(Detu)4SO4] (1) is prepared and its crystal structure is determined by X-ray crystallography. The crystal structure of the complex consists of an independent molecule with the central cadmium atom coordinated to four thione sulfur atoms of Detu and two oxygen atoms of the sulfate ligand. The Cd atom has a pseudo-octahedral coordination environment with the cis angles varying from 57.68° to 126.57°, while the trans angles fall in the range of 142° to 169°. The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding.

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Authors and Affiliations

  1. Institute of Physics, University of Neuchâtel, CH-2009, Neuchâtel, Switzerland

    M. Altaf & H. Stoeckli-Evans

  2. Department of Chemistry, University of Engineering and Technology, Lahore, 54890, Pakistan

    G. Murtaza & S. Ahmad

  3. Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia

    A. A. Isab

  4. Department of Chemistry, University of Sargodha, Sargodha, Pakistan

    M. A. Shaheen

Authors
  1. M. Altaf
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  2. H. Stoeckli-Evans
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  3. G. Murtaza
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  4. A. A. Isab
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  5. S. Ahmad
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  6. M. A. Shaheen
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Correspondence to S. Ahmad.

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Original Russian Text Copyright © 2011 by M. Altaf, H. Stoeckli-Evans, G. Murtaza, A.A. Isab, S. Ahmad, and M. A. Shaheen

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 52, No. 3, pp. 640–644, May–June, 2011.

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Altaf, M., Stoeckli-Evans, H., Murtaza, G. et al. Structural characterization of a cadmium(II)-sulfato complex, [Cd(N,N′-diethyl thiourea)4(SO4)]. J Struct Chem 52, 625–630 (2011). https://doi.org/10.1134/S0022476611030267

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  • DOI: https://doi.org/10.1134/S0022476611030267

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