Abstract
The paper considerations of the possibility of the low-temperature (1000°C) and high-temperature (>1500°C) thermal decomposition of solid samples of suspensions and the selective fractional evaporation–condensation of elements in specialized electrothermal crucible and rod atomizers for the purposes of direct atomic-absorption analysis. The approach is applied to analyze samples of riverine and marine suspensions for Ag, Cd, and Tl.
References
V. V. Gordeev and V. N. Oreshkin, “Silver, cadmium, and lead in the waters, tributaries, and an estuary of the Amazon River,” Geokhimiya (2), 244–256 (1990).
V. V. Gordeev, Geochemistry of the River–Sea System (IPMatushkina, Moscow, 2012) [in Russian].
K. Govindaraju, “Compilation of working values and sample description for 272 geostandards,” Geostand. Newslet. 13 (Special Ed.), 1–113 (1989).
Yu. A. Karpov and A. P. Savostin, Methods of Sampling and Sample Preparation (BINOM, Laboratoriya Znanii, Moscow, 2003) [in Russian].
I. V. Kubrakova T. F. Kudinova, A. A. Formanovsky, H. M. Kuzmin, G. I. Tsisin, and Yu. A. Zolotov, “Determination of chromium (III) and chromium (VI) in river water by electrothermal atomic absorption spectrometry after sorption preconcentration in microwave field,” Analyst 119 (11), 24–27 (1994).
K. Yu. Nagulin, I. V. Tsivil’skii, R. I. Nazmiev, and A. Kh. Gil’mutdinov, “Numerical simulation of thermal and gas-geodynamic processes in the two-stage atomizer for analytical spectrometry,” Optich. Zh. 79 (12), 46–55 (2012).
V. N. Oreshkin and G. I. Tsizin, “Atomic absorption determination of elements in natural samples using a vaporization crucible with two condensation zones,” J. Analyt. Chem. 67 (10), 830–833 (2012).
V. N. Oreshkin and G. I. Tsizin, “Electrothermal atomic absorption determination of elements in natural waters and particulates after extraction of concentrates on the membrane filters,” Zavod. Lab. Diagnost. Material. 79 (3), 16–18 (2013).
V. N. Oreshkin and G. I. Tsizin, “Sorption–atomic absorption determination of metal ultratraces in marine and river particulate matter,” Geochem. Int. 41 (3), 345–349 (2003).
V. N. Oreshkin and Uu. G. Tatsy, “Direct atomic absorption determination of mercury traces in solid geochemical samples,” in Mercury in the Biosphere: Ecological–Geochemical Aspects (GEOKHI RAS, Moscow, 2010), pp. 372–376.
V. N. Oreshkin, G. I. Tsizin, and G. L. Vnukovskaya, “Sorption–atomic absorption determinations of metal traces (Ag, Bi, In, Cd, Pb, and Tl) in marine and river waters using two-chamber powder atomizer,” Zh. Analit. Chem. 49 (7), 755–759 (1994).
V. N. Oreshkin, G. I. Tsizin, and Yu. A. Zolotov, “Sorption–atomic absorption determination of trace elements in natural waters with dynamic preconcentration in electrothermal atomizers,” J. Analit. Chem. 57 (9), 778–783 (2002).
V. N. Oreshkin, Yu. I. Belyaev, and G. L. Vnukovskaya, “Atomizer of powders of geochemical samples and environmental objects for direct atomic absorption analysis,” Zavod. Lab. 56 (12), 50–53 (1990).
V. N. Oreshkin, Yu. I. Belyaev, Yu. G. Tatsy, and G. L. Vnukovskaya, “Electrothermal atomizer for nonflame atomic absorption analysis,” Byul. Izobret. 48, 291 (1986).
A. A. Pupyshev, Atomic Absorption Spectral Analysis (Tekhnosfera, Moscow, 2009) [in Russian].
V. S. Savenko, Chemical Composition of Suspended Sediments of Rivers and Seas (GEOS, Moscow, 2006) [in Russian]
Yu. A. Zakharov, O. B. Kokorina, Yu. V. Lysogorskii, and A. E. Staroverov, “Computer simulation of two-step atomization in graphite furnaces for analytical atomic spectrometry,” J. Analyt. Chem. 67 (8), 714–721 (2012).
Kh. I. Zil’bershtein, M. P. Semov, O. N. Nikitina, and Z. G. Fratikin, Spectral Analysis of Pure Substances (Khimiya, Leningrad, 1971) [in Russian].
Yu. A. Zolotov, G. I. Tsizin, S. G. Dmitrienko, and E. I. Morosanova, Sorption Concentration of Trace Components from Solutions (Nauka, Moscow, 2007) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.N. Oreshkin, G.I. Tsizin, Yu.G. Tatsii, 2018, published in Geokhimiya, 2018, No. 3, pp. 290–295.
Rights and permissions
About this article
Cite this article
Oreshkin, V.N., Tsizin, G.I. & Tatsii, Y.G. Specialized Methods of Thermal Treatment of Riverine and Marine Suspensions Preparatorily to Their Analysis for Trace Concentrations of Chemical Elements. Geochem. Int. 56, 276–281 (2018). https://doi.org/10.1134/S0016702918030060
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0016702918030060