Abstract
High fluoride and arsenic concentrations in groundwater have led to serious health problems to local inhabitants at Yuncheng basin, Northern China. In this study, groundwater with high fluoride and arsenic concentration at Yuncheng basin was investigated. A majority of the samples (over 60%) belong to HCO3 type water. The predominant water type for the shallow groundwater collected from southern and eastern mountain areas was Ca/Mg-Ca-HCO3 types. For the shallow groundwater from flow through and discharge area it is Na-HCO3/SO4-Cl/SO4/Cl type. The predominant water type for the intermediate and deep groundwater is of Na/Ca/Mg-Ca-HCO3 type. According to our field investigation, fluoride concentration in groundwater ranges between 0.31 and 14.2 mg/L, and arsenic concentration ranges between 0.243 and 153.7 μg/L. Out of seventy collected groundwater samples, there are 31 samples that exceed the World Health Organization (WHO) standard of 1.5 mg/L for fluoride, and 15 samples exceeds the WHO standard of 10 μg/L for arsenic. Over 40% of high fluoride and arsenic groundwater are related to the Na-HCO3 type water, and the other fifty percent associated with Na-SO4-Cl/HCO3-SO4-Cl type water; little relation was found in calcium bicarbonate type water. A moderate positive correlation between fluoride and arsenic with pH were found in this study. It is due to the pH-dependent adsorption characteristics of F and As onto the oxide surfaces in the sediments. The observed negative correlation between fluoride and calcium could stem from the dissolution equilibrium of fluorite. The high concentration of bicarbonate in groundwater can serve as a powerful competitor and lead to the enrichment of fluoride and arsenic in groundwater. Most of the groundwater with high fluoride or arsenic content has nitrate content about or over 10 mg/L which, together with the observed positive correlations between nitrate and fluoride/arsenic, are indicative of common source of manmade pollution and of prevailing condition of leaching in the study area.
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References
D. M. Allen and M. Suchy “Geochemical evolution of groundwater on Saturna Island, British Columbia,” Earth Sci. 38, 1059–1080 (2001).
Z. An, G. J. Kukla, S. C. Porter, and J. Xiao, “Magnetic susceptibility evidence of monsoon variation on the Loess Plateau of central China during the last, 130,000 years,” Quatern. Res. 36, 29–39 (1991).
F. Chen, J. Li, and W. Zhang, “Lanzhou loess profile and its comparison with deep sea sediment and Antarctic ice core,” Geol. J. 24(2), 201–209 (1991).
S. Chouhan and S. J. S. Flora, “Arsenic and fluoride: Two major groundwater pollutants,” Indian J. Exp. Biol. 48, 666–678 (2010).
M. J. Currell, I. Cartwrite, D. C. Brandley, and D. M. Han, “Recharge history and controls on groundwater quality in the Yuncheng Basin, north China,” Hydrol. 385, 216–229 (2010).
M. J. Currell, I. Cartwrite, R. Massimo, and D. M. Han, “Control on elevated fluoride and arsenic concentrations in groundwater from the Yuncheng basin,” China. Appl. Geochem. 25, 540–552 (2011).
W. M. Edmunds, “Renewable and non-renewable groundwater in semi-arid regions,” Water Sci. 50, 265–280 (2003).
X. B. Gao, Y. X. Wang, Y. Li, and Q. Guo, “Enrichment of fluoride in groundwater under the impact of saline water intrusion at the salt lake area of Yuncheng basin, northern China,” Environ. Geol. 53, 795–803 (2007).
X. B. Gao, Y. X. Wang, Q. H. Hu, and C. L. Su, “Effects of anion competitive adsorption on arsenic enrichment in groundwater,” J. Environ. Sci. Health, Pt. A, 46, 1–9 (2011).
X. B. Gao, C. C. Li, and Y. X. Wang, “Arsenic in saline groundwater in the Yuncheng Basin, North China. Understanding the geological and medical interface of arsenic,” in Proceedings of the 4th International Congress on Arsenic in the Environment, Cairns, Australia, 2012, Ed. by Jack C. Ng, Barry N. Noller, Ravi Naidu, Jochen Bundschuh, and Prosun Bhattacharya, CRC Press, 547–549 (2012).
Groundwater Resources and Environmental Issues Assessment in the Six Major Basins of Shanxi. Geological Survey Report (China, 2006).
J. D. Hem, “Study and interpertation of the chemical charateristics of natural water, Jodhpur, India,” US Geol. Surv. Prof. Pap., No. 2254, (1991).
H. Kashiwagi, N. Shikazono, Y. Ogawa, Y. Hihuhhi, M. Takahashi, and Y. Tanaka, “Mineralogical and biological influences on groundwater chemistry of the Boso Peninsula, Chiba, central Japan: Implications for the origin of groundwater in sedimentary basins,” Geochem. J. 40, 345–361 (2006).
X. Li, “Pressure of water shortage on agriculture in arid region of China,” China Geog. Sci. 13, 124–129 (2003).
D. S. Liu, Loess in China (China Ocean Press, Beijing, 1988).
W. W. McNab Jr, M. J. Signleton, J. E. Moran, and B. K. Esser, “Ion exchange and trace element surface complexation reactions associated with applied recharge of low-TDS water in the San Joaquin valley, California,” Appl. Geochem. 24, 129–197 (2009).
B. W. Oyelola and Z. H. Tang, “Development of a three-dimensional numerical model to evaluate groundwater resource flow of the Yuncheng Basin,” J. Appl. Sci. 8, 966–974 (2008).
D. L. Parkhurst and C. A. J. Apello, “User’s guide to PHREEQC (version, 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations,” US Geol. Surv. Water Resour. Invest. Rep., No. 99-4259. (1999).
Patrick H. Masscheleyn, Ronald D. Delaune, and William H. Patrick, Jr, “Effect of redox potential and pH on arsenic speciation and solubility in a contaminated soil,” Environ. Sci. Technol. 25(8), 1991.
M. L. Pierce and C. B. Moore, “Adsorption of arsenite and arsenate on amorphous ironhydroxide,” Water Res. 16, 1247–1253 (1982).
N. Subha Rao, “Fluoride in groundwater, Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India,” Environ. Monit. Assess. 152, 47–60 (2009).
B. R. Scanlon, J. P. Nicot, R. C. Reedy, D. Kurtzman, A. Mukherjee, and D. K. Nordstrom, “Elevated naturally occurring arsenic in a semiarid oxidizing system, Southern High Plains aquifer, Texas, USA,” Appl. Geochem. 24, 2061–2071 (2009).
E. B. Shaji, J. Vijiu, and D. S. Thambi, “High fluoride in groundwater of Palghat Distric, Kerala,” Current Sci. 92, 240–245 (2007).
P. L. Smedley and D. G. Kinniburgh, “A review of the source, behaviour and distribution of arsenic in natural water,” Appl. Geochem. 17, 517–568 (2002).
E. Smith, R. Nadiu, and A. M. Alston, “Chemistry of inorganic arsenic in soils: II. Effect of phosphorous, sodium and calcium on arsenic sorption,” Environ. Qual. 31, 557–563 (2002).
Q. Wang, C. Li, G. Tian, W. Zhang, and C. Liu, “Tremendous change of the earth surface system and techonic setting of salt-lake formation in Yuncheng basin since 7.1 Ma,” Sci. China Earth Sci-Ser. D 45(2), 110–122 (2002).
WHO Guidelines for Drinking Water Quality, First addendum to third edition (World Health Organization, Geneva, 2006).
WHO Gudielines for Drinking-Water. Volume 2. Health Criteria and Other Supporting Information (World Health Organization, Geneva, 1984).
WHO Environmental Health Criteria 224: Arsenic and Arsenic Compounds, (World Health Organization, Geneva.2001).
M. Yu, Environmental Toxicology. Biological and Health Effects of Pollutants (CRC Press, Boca Ranton, 2005).
Yuncheng Regional Water Bureau; Shanxi Geological Survey Hydrological and Geological Maps and Explanations for the Yuncheng Region, 1: 100000. Shanxi Geological Survey Special Report (Yuncheng Regional Water Bureau, Yuncheng City, 1982) (in Chinese).
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Khair, A.M., Li, C., Hu, Q. et al. Fluoride and arsenic hydrogeochemistry of groundwater at Yuncheng basin, Northern China. Geochem. Int. 52, 868–881 (2014). https://doi.org/10.1134/S0016702914100024
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DOI: https://doi.org/10.1134/S0016702914100024