Abstract
The Rayleigh–Benard convection in a chemically active gas in the chemical equilibrium state is numerically studied in the Boussinesq approximation. A flat layer with isothermal horizontal boundaries free from shear stresses is considered. Thermodynamic parameters of the gas (hydrogen–oxygen mixture) are calculated by the previously proposed model of chemical equilibrium. It is shown that the allowance for recombination and dissociation processes leads to the emergence of an additional factor at the Rayleigh number. An expression for the growth rate of infinitesimal perturbations and a relation for the critical Rayleigh number as a function of temperature are derived. It is found that the neutral curves consist of the upper (instability due to heating from below) and lower (instability due to heating from above) branches. Results calculated for a nonlinear steady mode are reported.
Similar content being viewed by others
References
G. Z. Gershuni and E. M. Zhukhovitskii, Convective Stability of an Incompressible Fluid (Nauka, Moscow, 1972) [in Russian].
I. B. Palymskiy, Turbulent Rayleigh–Benard Convection. Numerical Method and Calculated Results (LAP, Germany, 2011).
V. M. Paskonov, V. I. Polezhaev, and L. A. Chudov, Numerical Simulation of Heat and Mass Transfer (Nauka, Moscow, 1984) [in Russian].
I. B. Palymskiy, “Linear and Nonlinear Analysis of the Numerical Method of Calculating Convective Flows,” Sib. Zh. Vychisl. Mat. 7 (2), 143–163 (2004).
Yu. A. Nikolaev, “Model of the Kinetics of Chemical Reactions at High Temperatures,” Fiz. Goreniya Vzryva 14 (4), 73–76 (1978) [Combust., Expl., Shock Waves 14 (4), 468–471 (1978)].
Yu. A. Nikolaev and P. A. Fomin, “Analysis of Equilibrium Flows of Chemically Reacting Gases,” Fiz. Goreniya Vzryva 18 (1), 66–72 (1982) [Combust., Expl., Shock Waves 18 (1), 53–58 (1982)].
Yu. A. Nikolaev and P. A. Fomin, “Approximate Equation of Kinetics in Heterogeneous Systems of the Gas–Condensed-Phase Type,” Fiz. Goreniya Vzryva 19 (6), 49–58 (1983) [Combust., Expl., ShockWaves 19 (6), 737–745 (1983)].
Yu. A. Nikolaev and D. V. Zak, “Agreement of Models of Chemical Reactions in Gases with the Second Law of Thermodynamics,” Fiz. Goreniya Vzryva 24 (4), 87–90 (1988) [Combust., Expl., Shock Waves 24 (4), 461–463 (1988)].
P. A. Fomin and A. V. Trotsyuk, “An Approximate Calculation of the Isentrope of a Gas in Chemical Equilibrium,” Fiz. Goreniya Vzryva 31 (4), 59–62 (1995) [Combust., Expl., Shock Waves 31 (4), 455–458 (1995)].
I. Palymskiy, P. A. Fomin, and H. Hieronymus, “Rayleigh–Benard Convection in Chemical Equilibrium Gas,” Prog. Comput. Heat Mass Transfer 1, 116–122 (2005) [in Proc. of the Fourth Int. Conf. on Computational Heat and Mass Transfer (ICCHMT’05), Paris, France, May 17–20, 2005].
I. B. Palymskiy, P. A. Fomin, and H. Hieronymus, “Rayleigh–Benard Convection in a Gas with Chemical Reactions,” Sib. Zh. Vychisl. Mat. 10 (4), 371–383 (2007).
I. Palymskiy, P. A. Fomin, and H. Hieronymus, “Rayleigh–Benard Convection in a Chemical Equilibrium Gas (Simulation of Surface Detonation Wave Initiation),” Appl. Math. Model. 32 (5), 660–676 (2008).
I. B. Palymskiy, V. I. Palymskiy, A. V. Trilis, and A. V. Trifanov, “Numerical Simulation of Convective Flows in Reacting Gas Mixtures,” in Proc. XIX Int. Conf. on Computational Mechanics and Advanced Applied Systems (VMSPPS’2015), Alushta, Crimea, May 24–31, 2015, pp. 506–508.
A. V. Getling, Rayleigh–Benard Convection. Structure and Dynamic (Editorial URSS, Moscow, 1999) [in Russian].
D. V. Voronin, “Nonideal Detonation in a Smooth Pipe,” Fiz. Goreniya Vzryva 25 (2), 116–124 (1989) [Combust., Expl., Shock Waves 25 (2), 237–243 (1989)].
A. V. Trotsyuk, “Numerical Simulation of the Structure of Two-Dimensional Gas Detonation in an H2–O2–Ar Mixture,” Fiz. Goreniya Vzryva 35 (5), 93–103 (1999) [Combust., Expl., Shock Waves 35 (5), 549–558 (1999)].
A. A. Vasil’ev and A. V. Trotsyuk, “Experimental Investigation and Numerical Simulation of an Expanding Multifront Detonation Wave,” Fiz. Goreniya Vzryva 39 (1), 92–103 (2003) [Combust., Expl., Shock Waves 39 (1), 80–90 (2003)].
Yu. A. Nikolaev and P. A. Fomin, “A Model for Stationary Heterogeneous Detonation in a Gas–Droplet Mixture,” Fiz. Goreniya Vzryva 20 (4), 97–105 (1984) [Combust., Expl., Shock Waves 20 (4), 447–454 (1984)].
D. V. Voronin, “Detonation in a Cryogenic Hydrogen–OxygenMixture,” Fiz. Goreniya Vzryva 20 (4), 105–112 (1984) [Combust., Expl., Shock Waves 20 (4), 455–460 (1984)].
S. A. Zhdan and E. S. Prokhorov, “Calculation of the Cellular Structure of Detonation of Sprays in an H2–O2 System,” Fiz. Goreniya Vzryva 36 (6), 111–118 (2000) [Combust., Expl., Shock Waves 36 (6), 777–784 (2000)].
P. A. Fomin, K. S. Mitropetros, and H. Hieronymus, “Modeling of Detonation Processes in Chemically Active Bubble Systems at Normal and Elevated Initial Pressures,” J. Loss Prev. Process Ind. 16 (4), 323–331 (2003).
S. A. Zhdan, “Detonation of a Column of a Chemically Active Bubbly Medium in a Liquid,” Fiz. Goreniya Vzryva 39 (4), 107–112 (2003) [Combust., Expl., Shock Waves 39 (4), 458–463 (2003)].
P. A. Fomin and J.-R. Chen, “Shock Induced Condensation in a Fuel-Rich Oxygen Containing Bubble in a Flammable Liquid,” Chem. Eng. Sci. 63 (3), 696–710 (2008).
P. A. Fomin, “Model of Steady Heterogeneous detonation in a Gas–Film System for Fuel-Rich Mixtures,” in Dynamics of Continuous Media, No. 73: Mechanics of Fast Processes (Inst. of Hydrodynamics, Sib. Branch, USSR Acad. of Sci., Novosibirsk, 1985), pp. 122–136.
T. P. Gavrilenko, V. V. Grigoriev, S. A. Zhdan, et al., “Acceleration of Solid Particles by Gaseous Detonation Products,” Combust. Flame 66 (2), 121–128 (1986).
S. A. Zhdan, V. V. Mitrofanov, and A. I. Sychev, “Reactive Impulse from the Explosion of a Gas Mixture in a Semiinfinite Space,” Fiz. Goreniya Vzryva 30 (5), 90–97 (1994) [Combust., Expl., Shock Waves 30 (5), 657–663 (1994)].
S. A. Zhdan and F. A. Bykovskii, Continuous Spin Detonation (Izd. Sib. Otd. Ross. Akad. Nauk, Novosibirsk, 2013) [in Russian].
P. A. Fomin and J.-R. Chen, “Effect of Chemically Inert Particles on Thermodynamic Characteristics and Detonation of a Combustible Gas,” Combust. Sci. Technol. 181 (8), 1038–1064 (2009).
A. V. Fedorov, P. A. Fomin, V. M. Fomin, et al., Mathematical Analysis of Detonation Suppression by Inert Particles (Kao Tech., Kaohsiung, Taiwan, 2012).
P. A. Fomin, A. V. Fedorov, and J.-R. Chen, “Control of Explosions in Silane–Air Mixtures by means of Chemically Inert Microparticles,” in Proc. of the Tenth Intern. Symp. on Hazards, Prevention and Mitigation of Industrial Explosions (X ISHPMIE) (Bergen, Norway, June 10–14, 2014), pp. 951–958.
P. A. Fomin and J.-R. Chen, “New Simple Method for Calculation Flammability Limits of Mixtures of Flammable Fuels,” IChemE Symp. Ser., No. 153 (2007), Paper No. 104 (in Proc. 12th Int. Symp. on Loss Prevention and Safety Promotion in the Process Industries).
K. A. Nadolin, “On Penetrating Convection in the Approximation of an Isothermally Incompressible Fluid,” Izv. Ross. Akad. Nauk, Mekh. Zhidk. Gaza, No. 2, 40–52 (1996).
K. I. Babenko and A. I. Rakhmanov, “Numerical Study of Two-Dimensional Convection,” Preprint No. 11 (Keldysh Institute of Applied Mathematics, Acad. of Sci. of the USSR, Moscow, 1988).
I. B. Palymskiy, “Asymptotic Mode of the Rayleigh–Benard Convection,” Vestn. Yuzhno-Uralsk. Univ., Ser. Mat. Mekh. Fiz. 7 (4), 61–67 (2015).
I. K. Kikoin, Tables of Physical Quantities: Reference Book (Atomizdat, Moscow, 1976) [in Russian].
http://www.highexpert.ru/content/gases/air.html.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.B. Palymskiy, V.I. Palymskiy, P.A. Fomin.
Published in Fizika Goreniya i Vzryva, Vol. 53, No. 2, pp. 3–14, March–April, 2017.
Rights and permissions
About this article
Cite this article
Palymskiy, I.B., Palymskiy, V.I. & Fomin, P.A. Rayleigh–Benard convection in a chemically active gas in the chemical equilibrium state. Combust Explos Shock Waves 53, 123–133 (2017). https://doi.org/10.1134/S0010508217020010
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0010508217020010