Abstract
The initial stage of phase separation of binary Fe–22 at % Cr alloy during thermal aging at 500°C is studied at the atomic-scale level by atom probe tomography. Upon the behavior analysis of pair-correlation function of chromium atoms, long-range correlations typical of spinodal decomposition are observed at short aging times, which disappear 25 h after aging. The analysis of 3D atomic maps shows that Cr-rich regions form at the initial steps of decomposition, where the chromium concentration increases with an increase in the aging time. At the aging time of ~100 h, the chromium concentration in the center of these regions reaches 80 at %, which corresponds to the α' phase.
Similar content being viewed by others
References
Beskorovainy, N.M., Kalin, B.A., and Chernov, I.I., Konstruktsionnye materialy yadernykh reaktorov (Structural Materials of Nuclear Reactors), Moscow: Energoatomizdat, 1995.
Klueh, R.L. and Harries, D.R., High-Chromium Ferritic and Martensitic Steels for Nuclear Applications, ASTM International, 2001.
Rogozhkin, S.V., Nikitin, A.A., Aleev, A.A., Germanov, A.B., and Zaluzhnyi, A.G., Atom probe study of radiation induced precipitates in Eurofer97 ferritic–martensitic steel irradiated in BOR-60 reactor, Inorg. Mater.: Applied Res., 2013, vol. 4, pp. 112–118.
Andersson, J.O. and Sundman, B., Thermodynamic properties of the Cr–Fe system, Calphad, 1987, vol. 11, no. 1, pp. 83–92.
Xiong, W., Hedstrom, P., Selleby, M., Odqvist, J., Thuvander, M., and Chen, Q., An improved thermodynamic modeling of the Fe–Cr system down to zero Kelvin coupled with key experiments, Calphad, 2011, vol. 35, no. 3, pp. 355–366.
Nikolaev, A.L., Specificity of stage III in electron-irradiated Fe–Cr alloys, Philos. Mag., 2007, vol. 87, no. 31, pp. 4847–4874.
Nikolaev, A.L. and Kurennykh, T.E., On the interaction between radiation-induced defects and foreign interstitial atoms in α-iron, J. Nucl. Mater., 2011, vol. 414, no. 3, pp. 374–381.
Suvorov, A.L., Rogozhkin, S.V., Zaluzhnyi, A.G., Aleev, A.A., Bobkov, A.F., Zaitsev, S.V., Karpov, A.V., Kozodaev, M.A., Loginov, B.A., and Makeev, O.N., Atomic-scaled studies of reactor materials, Vopr. At. Nauki Tekh., Ser. Materialoved. Nov. Mater, 2006, no. 1, pp. 3–13.
Miller, M.K., Atom Probe Tomography: Analysis at the Atomic Level, Berlin: Springer-Verlag, 2000.
Philippe, T., Duguay, S., and Blavette, D., Clustering and pair correlation function in atom probe tomography, Ultramicroscopy, 2010, vol. 110, no. 7, pp. 862–865.
Miller, M.K., Hyde, J.M., Hetherington, M.G., Cerezeo, A., Smith, G.D.W., and Elliot, C.M., Spinodal decomposition in Fe–Cr alloys: Experimental study at the atomic level and comparison with computer models-1: Introduction and methodology, Acta Metallur. Mater., 1995, vol. 43, no. 9, pp. 3385–3401.
Dubiel, S.M. and Inden, G., Möessbauer-effect determination of the miscibility gap in the Fe–Cr system, Zt. Metallkd., 1987, vol. 78, no. 8, pp. 544–549.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.V. Rogozhkin, O.A. Korchuganova, A.A. Aleev, 2015, published in Perspektivnye Materialy, 2015, No. 12, pp. 34–39.
Rights and permissions
About this article
Cite this article
Rogozhkin, S.V., Korchuganova, O.A. & Aleev, A.A. Kinetics of α’-phase nucleation during thermal aging of Fe–22% Cr alloy. Inorg. Mater. Appl. Res. 7, 210–213 (2016). https://doi.org/10.1134/S2075113316020179
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2075113316020179