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Composites based on polyaniline and aligned carbon nanotubes

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Abstract

Composites based on aligned carbon nanotubes and polyaniline are prepared via the electrochemical polycondensation of aniline in a sulf uric acid solution. The structure of the composites and the character of interaction of polyaniline and the surface of carbon nanotubes are studied by scanning and transmission electron microscopy, X-ray diffraction, and IR and X-ra y photoelectron spectroscopy. It is shown that in the composites, electron density is transferred from the carbon nanotube to the polyaniline film. The occurrence of polyaniline on the surface of nanotubes increases the mean current in cyclic voltammograms of the composite material and leads to a marked increase in the calculated specific capacity of electrodes formed on its basis.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. V. Okotrub, I. P. Asanov, P. S. Galkin, L. G. Bulusheva, G. N. Chekhova, A. G. Kurenya & Yu. V. Shubin

  2. Novosibirsk State Technical University, ul. Karla Marksa 20, Novosibirsk, 630092, Russia

    A. G. Kurenya

Authors
  1. A. V. Okotrub
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  2. I. P. Asanov
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  3. P. S. Galkin
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  4. L. G. Bulusheva
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  5. G. N. Chekhova
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  6. A. G. Kurenya
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  7. Yu. V. Shubin
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Corresponding author

Correspondence to A. V. Okotrub.

Additional information

Original Russian Text © A.V. Okotrub, I.P. Asanov, P.S. Galkin, L.G. Bulusheva, G.N. Chekhova, A.G. Kurenya, Yu.V. Shubin, 2010, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2010, Vol. 52, No. 2, pp. 351–359.

This work was supported by the program Leading Scientific Schools (NSh 636.2008.3) and the special-purpose program Development of the Scientific Potential of the Higher School (RNP 2.1.2.5257 and 2.1.2.2115).

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Okotrub, A.V., Asanov, I.P., Galkin, P.S. et al. Composites based on polyaniline and aligned carbon nanotubes. Polym. Sci. Ser. B 52, 101–108 (2010). https://doi.org/10.1134/S1560090410010161

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  • DOI: https://doi.org/10.1134/S1560090410010161

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