Skip to main content
SpringerLink
Log in

Synthesis and molecular structure of 1-(2-pyridyloxy)silatrane

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

1-(2-Pyridyloxy)silatrane was synthesized by trans-etherification of 1-ethoxysilatrane with 2-hydroxypyridine as well as by the reaction of the latter with tetraethoxysilane and triethanolamine. Its structure was established by the XRD analysis of a single crystal, and in solution using the methods of 1H, 13C, 29Si NMR and IR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Voronkov, M.G., Lukina, Yu.A., Tandura, S.N., Voronov, V.K., and D’yakov, V.M., Zh. Obshch. Khim., 1979, vol. 49, no. 6, p. 1278.

    CAS  Google Scholar 

  2. Voronkov, M.G. and Zelchan, G.I., Khim. Geterotsicl. Soed., 1965, no. 2, p. 210.

  3. Voronkov, M.G. and Zelchan, G.I., Khim. Geterotsicl. Soed., 1966, no 4, p. 511.

  4. Iovel, I., Colombo., L., Popelis Yu., Grinberga, S., and Lukevics, E., Khim. Geterotsicl. Soed., 1999, no. 9, p. 1203.

  5. Minkin, V.I., Olekhnovich, L.P., and Zhdanov, Yu.A., Molekulyarnyi dizain tautomernykh system (Molecular Design of Tautomeric Systems)., Rostov-na-Donu, 1977.

  6. Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Zakrzewski, V.G., Montgomery, J.A., Stratmann, R.E., Burant, J.C., Dapprich, S., Millam, J.M., Daniels, A.D., Kudin, K.N., Strain, M.C., Farkas, O., Tomasi, J., Barone, V., Cossi, M., Cammi, R., Mennucci, B., Pomelli, C., Adamo, C., Clifford, S., Ochterski, J., Petersson, G.A., Ayala, P.Y., Cui, Q., Morokuma, K., Malick, D.K., Rabuck, A.D., Raghavachari, K., Foresman, J.B., Cioslowski, J., Ortiz, J.V., Stefanov, B.B., Liu, G., Liashenko, A., Piskorz, P., Komaromi, I., Gomperts, R., Martin, R.L., Fox, D.J., Keith, T., Al-Laham, M.A., Peng, C.Y., Nanayakkara, A., Gonzalez, C., Challacombe, M., Gill, P.M.W., Johnson, B., Chen, W., Wong, M.W., Andres, J.L., Gonzalez, C., Head-Gordon, M., Replogle, E.S., and Pople, J.A., Gaussian 98, Revision, A.6, Gaussian, Pittsburgh, 1998.

  7. Lin Xiuyun, Zheng Qitai, Wu Shen, Zhang Shude, Shen Fuling, Wang Jitao, Xie Qinglan, Liao Renan, and Li Jing, Gaodeng Xuexiao Huaxue Xuebao, 1987, vol. 8, no. 7, p. 629, C. A., 1988, vol. 108, no. 10, p. 698.

    CAS  Google Scholar 

  8. Kovacs, I., Hencsei, P., and Parkanyi, L., Period. Polytech., Chem. Eng., 1987, vol. 31, no. 3, p. 155, C. A., 1987, vol. 107, no. 26, p. 706 (247206b).

    CAS  Google Scholar 

  9. Tasaka, M., Hirotsu, M., Kojima, M., Utsuno, S., and Yoshikawa, Yu., Inorg. Chem., 1996, vol. 35, no. 24, p. 6981.

    Article  CAS  Google Scholar 

  10. Garant, R.J., Daniels, L.M., Das, S.K., Janakiraman, M.N., Jacobson, R.A., and Verkade, J.G., J. Am. Chem. Soc., 1991, vol. 113, no. 15, p. 5728.

    Article  CAS  Google Scholar 

  11. Korlyukov, A.A., Lyssenko, K.A., Antipin, M.Yu., Knyazev, S.P., Kirin, V.N., Vasilev, I.M., and Chernyshev, E.A., Zh. Neorg. Khim., 2003, vol. 48, no. 11, p. 1624.

    Google Scholar 

  12. Macharashvili, A.A., Shklover, V.E., Struchkov, Yu.T., Baryshok, V.P., and Voronkov, M.G., Dokl. Akad. Nauk SSSR, 1987, vol. 297, no. 5, p. 1123.

    CAS  Google Scholar 

  13. Vereshchagin, A.N., Induktivnyi effect. Konstanty zamestitelei dlya korrelyatsionnogo analiza (Inductive Effect. Constants of Substituents for the Correlation Analysis), Moscow, Nauka, 1988.

    Google Scholar 

  14. Voronkov, M.G. and Belyaeva, V.V., Russ. J. Gen. Chem., 2002, vol. 72, no. 12, p. 1904.

    Article  CAS  Google Scholar 

  15. Kirby, A., Anomernyi effect kislorodsoderzhashchikh soedinenii (Anomeric Effect of Oxygen-containing Compounds), Moscow: Mir, 1985.

    Google Scholar 

  16. Arshinova, R.P., Metallorg. Khim. 1990, vol. 3, no. 5, p. 1127.

    CAS  Google Scholar 

  17. Voronkov, M.G., Zelbst, E.A., Kashaev, A.A., Katkevich, A.V., Fundamenskii, V.S., Bruskov, V.A., Abumov, P.F., and Belyaeva, V.V., Dokl Chem., 2007, vol. 414, no. 1, p. 101.

    Article  CAS  Google Scholar 

  18. Shen, Q., J. Mol. Struct., 1979., vol. 51, no. 1, p. 61.

    Article  CAS  Google Scholar 

  19. Voronkov, M.G. and Zelchan, G.I., Metody polucheniya khimicheskikh reaktivov (Methods of Preparation of Chemical Reagents), Moscow: IREA, 1966, issue 14, p. 159.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    M. G. Voronkov, E. A. Zelbst, Yu. I. Bolgova, O. M. Trofimova, A. I. Albanov, N. N. Chipanina & T. N. Aksamentova

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    A. A. Korlyukov & M. Yu. Antipin

Authors
  1. M. G. Voronkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Zelbst
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. I. Bolgova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. M. Trofimova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. I. Albanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. N. Chipanina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. T. N. Aksamentova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. A. Korlyukov
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. M. Yu. Antipin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. G. Voronkov.

Additional information

Original Russian Text © M.G. Voronkov, E.A. Zelbst, Yu.I. Bolgova, O.M. Trofimova, A.I. Albanov, N.N. Chipanina, T.N. Aksamentova, A.A. Korlyukov, M.Yu. Antipin, 2008, published in Zhurnal Obshchei Khimii, 2008, Vol. 78, No. 12, pp. 1988–1993.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Voronkov, M.G., Zelbst, E.A., Bolgova, Y.I. et al. Synthesis and molecular structure of 1-(2-pyridyloxy)silatrane. Russ J Gen Chem 78, 2333–2338 (2008). https://doi.org/10.1134/S1070363208120074

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363208120074

Keywords

Search

Navigation