Skip to main content
Log in

2-(N-tosylamino)benzaldehyde thiobenzoylhydrazone and its complexes with copper(II) and zinc(II): Synthesis and structures

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

2-(N-Tosylamino)benzaldehyde thiobenzoylhydrazone and its copper(II) and zinc(II) complexes with dimethylformamide (DMF) and methanol, [CuL(DMF)] and [ZnL(CH3OH)], respectively, were synthesized. The structures of the copper(II) complex and the cyclic product of hydrazone oxidation (1,3,4-thiadiazole derivative) were determined by X-ray diffraction analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Zelenin, K.N., Khorseeva, L.A., and Alekseev, V.V., Khim. Farm. Zh., 1992, no. 5, p. 30.

    Google Scholar 

  2. West, D.X., Padhye, S.B., and Sonawane, P.B., Struct. Bond, 1991, vol. 76, p. 1.

    Article  CAS  Google Scholar 

  3. Pandeya, S.N. and Dimmock, J.R., Pharmazie, 1993, vol. 48, no. 9, p. 659.

    CAS  Google Scholar 

  4. Quiroga, A.G. and Ranninger, C.N., Coord. Chem. Rev., 2004, vol. 248, nos. 1–2, p. 119.

    Article  CAS  Google Scholar 

  5. Yu, Y., Kalinowski, D.S., Kovacevic, Z., et al., J. Med. Chem., 2009, vol. 52, no. 17, p. 5271.

    Article  CAS  Google Scholar 

  6. Padhye, S. and Kauffman, G.B., Coord. Chem. Rev., 1985, vol. 63, no. 1, p. 127.

    Article  CAS  Google Scholar 

  7. West, D.X. and Liberta, A.E., Coord. Chem. Rev., 1993, vol. 123, nos. 1–2, p. 49.

    Article  CAS  Google Scholar 

  8. Casas, J.S., Garcia-Tasende, M.S., and Sordo, J., Coord. Chem. Rev., 2000, vol. 209, no. 1, p. 197.

    Article  CAS  Google Scholar 

  9. Lobana, T.S., Sharma, R., Bawa, G., and Khanna, S., Coord. Chem. Rev., 2009, vol. 253, nos. 7–8, p. 977.

    Article  CAS  Google Scholar 

  10. Popov, L.D., Morozov, A.N., Shcherbakov, I.N., et al., Usp. Khim., 2009, vol. 78, no. 7, p. 641.

    Article  Google Scholar 

  11. Paterson, B.M. and Donnely, P.S., Chem. Soc. Rev., 2011, vol. 40, no. 5, p. 3005.

    Article  CAS  Google Scholar 

  12. Kogan, V.A., Lukov, V.V., Nedzvedskii, V.S., and Abramova, N.A., Zh. Neorg. Khim., 1987, vol. 32, no. 5, p. 1158.

    CAS  Google Scholar 

  13. Larin, G.M., Yusupov, V.G., Karimov, M.M., and Parpiev, N.A., Koord. Khim., 1997, vol. 23, no. 1, p. 63.

    CAS  Google Scholar 

  14. Singh, N.K. and Agrawal, N.R., Indian J. Chem., Sect. A: Inorg., Bio-inorg., Phys., Theor. Anal. Chem., 1998, vol. 37, no. 3, p. 276.

    Google Scholar 

  15. Pelagatti, P., Venturini, A., Leporati, A., et al., Dalton Trans., 1998, no. 16, p. 2715.

    Google Scholar 

  16. Sawusch, S., Schilde, U., Lehmann, A., and Uhlemann, E., Inorg. Chim. Acta, 1998, vol. 277, no. 2, p. 219.

    Article  CAS  Google Scholar 

  17. Naik, A.D., Annigeri, S.M., Gangadharmath, U.B., et al., Transition Met. Chem., 2002, vol. 27, no. 3, p. 333.

    Article  CAS  Google Scholar 

  18. Naik, A., Annigeri, S., Gangadharmath, U., et al., Bull. Chem. Soc. Jpn., 2002, vol. 75, no. 10, p. 2161.

    Article  CAS  Google Scholar 

  19. Mahia, J., Maestro, M., Vazquez, M., et al., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 1999, vol. 55, no. 12, p. 2158.

    Article  Google Scholar 

  20. Gordon, A. and Ford, R., The Chemist’s Companion: A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.

    Google Scholar 

  21. SMART and SAINT. Release 5.0. Area Detector Control and Integration Software, Madison (WI, USA): Bruker AXS, Analytical X-Ray Instruments, 1998.

  22. Sheldrick, G.M., SADABS. A Program for Exploiting the Redundancy of Area-Detector X-Ray Data, Göttingen (Germany): Univ. of Göttingen, 1999.

    Google Scholar 

  23. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, no. 1, p. 112.

    Article  CAS  Google Scholar 

  24. Khimiya gidrazonov (The Chemistry of Hydrazones), Kitaev, Yu.P., Ed., Moscow: Nauka, 1977.

    Google Scholar 

  25. Zelenin, K.N. and Alekseev, V.V., Khim. Geterotsikl. Soedin., 1988, vol. 24, no. 1, p. 3.

    Google Scholar 

  26. Parpiev, N.A., Yusupov, V.G., Yakimovich, S.I., and Sharipov, Kh.T., Atsilgidrazony i ikh kompleksy s perekhodnymi metallami (Acylhydrazones and Their Transition Metal Complexes), Tashkent: Fan, 1988.

    Google Scholar 

  27. Rakitin, Yu.V. and Kalinnikov, V.T., Sovremennaya magnetokhimiya (Modern Magnetochemistry), St. Petersburg: Nauka, 1994.

    Google Scholar 

  28. Spek, A.L., J. Appl. Crystallogr., 2003, vol. 36, no. 1, p. 7.

    Article  CAS  Google Scholar 

  29. Gottlieb, H.E., Kotlyar, V., and Nudelman, A., J. Org. Chem., 1997, vol. 62, no. 21, p. 7512.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. I. Levchenkov.

Additional information

Original Russian Text © L.D. Popov, S.I. Levchenkov, I.N. Shcherbakov, A.A. Tsaturyan, Yu.P. Tupolova, Z.A. Starikova, A.S. Burlov, V.V. Lukov, V.A. Kogan, 2013, published in Koordinatsionnaya Khimiya, 2013, Vol. 39, No. 5, pp. 259–263.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Popov, L.D., Levchenkov, S.I., Shcherbakov, I.N. et al. 2-(N-tosylamino)benzaldehyde thiobenzoylhydrazone and its complexes with copper(II) and zinc(II): Synthesis and structures. Russ J Coord Chem 39, 367–372 (2013). https://doi.org/10.1134/S107032841304009X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S107032841304009X

Keywords

Navigation