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Coordination compounds of ambidentate 1-(H)alkyl-2-(2-pyridyl)benzimidazoles. Synthesis and crystal structure

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Abstract

Mono- and binuclear complexes of 2-(2-pyridyl)benzimidazole and its 1-alkyl-substituted derivatives with zinc dichloride were synthesized and structurally characterized. In terms of the competitive coordination problem, it was shown that pyridylbenzimidazole is an N,N-chelating ligand. The binuclear complex is formed through a dichloride bridge.

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, pr. Stachki 194/3, Rostov-on-Don, 344104, Russia

    A. S. Burlov, V. V. Chesnokov, Yu. V. Koshchienko, I. S. Vasil’chenko, A. I. Uraev, G. S. Borodkin & A. D. Garnovskii

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    A. S. Antsyshkina, G. G. Sadkov & V. S. Sergienko

  3. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    D. A. Garnovskii

Authors
  1. A. S. Burlov
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  2. A. S. Antsyshkina
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  3. G. G. Sadkov
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  4. V. V. Chesnokov
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  5. Yu. V. Koshchienko
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  6. D. A. Garnovskii
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  7. I. S. Vasil’chenko
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  8. A. I. Uraev
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  9. G. S. Borodkin
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  10. V. S. Sergienko
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  11. A. D. Garnovskii
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Corresponding author

Correspondence to A. D. Garnovskii.

Additional information

Original Russian Text © A.S. Burlov, A.S. Antsyshkina, G.G. Sadkov, V.V. Chesnokov, Yu. V. Koshchienko, D.A. Garnovskii, I.S. Vasil’chenko, A.I. Uraev, G.S. Borodkin, V.S. Sergienko, A.D. Garnovskii, 2010, published in Koordinatsionnaya Khimiya, 2010, Vol. 36, No. 12, pp. 918–924.

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Burlov, A.S., Antsyshkina, A.S., Sadkov, G.G. et al. Coordination compounds of ambidentate 1-(H)alkyl-2-(2-pyridyl)benzimidazoles. Synthesis and crystal structure. Russ J Coord Chem 36, 906–912 (2010). https://doi.org/10.1134/S1070328410120079

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  • DOI: https://doi.org/10.1134/S1070328410120079

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