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Heterometallic complexes of Co2+, Ni2+, and Zn2+ with the [RuNO(NO2)4OH]2− anion and pyridine: Synthesis, crystal structure, and thermolysis

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Abstract

Three new heteronuclear complexes [Ru(NO)(NO2)4(OH)M(Py)3] (M = Co2+, Ni2+, Zn2+) were synthesized and structurally characterized. In all compounds, the [Ru(NO)(NO2)4(OH)] fragment is coordinated to the M atom by a bridging OH and two bridging NO2 groups. The coordination environment of the metal also includes three pyridine nitrogen atoms. Thermal decomposition of cobalt and nickel complexes in an inert atmosphere yields bimetallic solid solutions.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    G. A. Kostin, A. O. Borodin, Yu. V. Shubin, N. V. Kurat’eva, V. A. Emelyanov & P. E. Plyusnin

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    M. R. Gallyamov

Authors
  1. G. A. Kostin
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  2. A. O. Borodin
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  3. Yu. V. Shubin
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  4. N. V. Kurat’eva
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  5. V. A. Emelyanov
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  6. P. E. Plyusnin
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  7. M. R. Gallyamov
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Corresponding author

Correspondence to G. A. Kostin.

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Original Russian Text © G.A. Kostin, A.O. Borodin, Yu.V. Shubin, N.V. Kurat’eva, V.A. Emelyanov, P.E. Plyusnin, M.R. Gallyamov, 2009, published in Koordinatsionnaya Khimiya, 2009, Vol. 35, No. 1, pp. 57–64.

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Kostin, G.A., Borodin, A.O., Shubin, Y.V. et al. Heterometallic complexes of Co2+, Ni2+, and Zn2+ with the [RuNO(NO2)4OH]2− anion and pyridine: Synthesis, crystal structure, and thermolysis. Russ J Coord Chem 35, 57–64 (2009). https://doi.org/10.1134/S1070328409010126

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  • DOI: https://doi.org/10.1134/S1070328409010126

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