Skip to main content
SpringerLink
Log in

The effect of γ-irradiation on laser ablation of polyketone

  • Radiation Chemistry
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Results of a pioneering study of the effect of laser radiation in vacuum on the surface of a polyketone (alternating terpolymer of ethylene, propylene, and carbon monoxide, POK) plate are presented. It has been found that laser beam irradiation leads to the surface heating of the plate, its melting, and the formation of a characteristic surface microrelief, an ablation crater, from which the gas flow of the ablation plume carries away products that are deposited on surfaces outside the laser beam area to form a coating with a chemical composition close to that of the substrate POK. A rim grows from molten POK around the crater. The melting point of the crystalline modification (377 K), the molecular flow temperature (427 K), and the molecular weight of the coating (25560) are much lower than those of the initial POK (464 K, 477 K, and 159200, respectively), thereby indicating laser-induced chain degradation of POK. The preliminary γ-irradiation of POK to a dose of 100 kGy enhances its laser ablation rate.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Lippert, T. and Dickinson, J.T., Chem. Rev., 2003, vol. 103, p. 453.

    Article  CAS  Google Scholar 

  2. Ashfold, M.N.R., Claeyssens, F., Fuge, G.M., and Henley, S.J., Chem. Soc. Rev., 2004, vol. 33, p. 23.

    Article  CAS  Google Scholar 

  3. Chrisey, D.B., Pique, A., McGill, R.A., Horwitz, J.S., and Ringeisen, B.R., Chem. Rev., 2003, vol. 103, p. 553.

    Article  CAS  Google Scholar 

  4. Lippert, T., Adv. Polym. Sci., 2004, vol. 168, p. 51.

    Article  CAS  Google Scholar 

  5. Lippert, T., Plasma Process. Polym., 2005, vol. 2, p. 525.

    Article  CAS  Google Scholar 

  6. Urech, L. and Lippert, T., in Invited Chapter in Laser Ablation and Its Applications, Springer Series in Optical Sciences, vol. 129, Phipps, C., Ed., Berlin: Springer, 2007, p. 281.

  7. Urech, L., Lippert, T., Phipps, C.R., and Wokaun, A., Appl. Surf. Sci., 2007, vol. 253, p. 6409.

    Article  CAS  Google Scholar 

  8. Nagel, M., Hany, R., Lippert, T., Molberg, M., Nuesch, F.A., and Rentsch, D., Macromol. Chem. Phys., 2007, vol. 208, p. 277.

    Article  CAS  Google Scholar 

  9. Belov, G.P. and Novikova, E.V., Usp. Khim., 2004, vol. 73, p. 292.

    Article  Google Scholar 

  10. Tolstopyatov, E.M., Ivanov, L.F., Grakovich, P.N., and Krasovsky, A.M., Proc. SPIE—Int. Soc. Opt. Eng., 1998, vol. 3343, p. 1010.

    CAS  Google Scholar 

  11. Tolstopyatov, E.M., Doctoral (Tekh.) Dissertation, Gomel, 2007.

    Google Scholar 

  12. Tolstopyatov, E.M., J. Phys. D: Appl. Phys, 2005, vol. 38, p. 1993.

    Article  CAS  Google Scholar 

  13. Tolstopyatov, E.M., Allayarov, S.R., Grakovich, P.N., Ol’khov, Yu.A., and Kalinin, L.A., Plast. Massy, 2012, p. 13.

    Google Scholar 

  14. Tolstopyatov, E.M., J. Phys. D: Appl. Phys, 2005, vol. 38, p. 1993.

    Article  CAS  Google Scholar 

  15. Ol’khov, Yu.A., Allayarov, S.R., Tolstopyatov, E.M., Grakovich, P.N., Kalinin, L.A., Dobrovol’skii, Yu.A., and Dixon, D.A., High Energy Chem., 2010, vol. 44, no. 1, p. 63.

    Article  Google Scholar 

  16. Ol’khov, Yu.A., Allayarov, S.R., and Kochetkova, G.V., in Sbornik nauchnykh trudov: “Soedinenie ftora. Khimiya, Tekhnologiya, primenenie” (Collection of Articles: Fluorine Compounds: Chemistry, Technology and Application), St. Petersburg: Teza, 2009, p. 227.

    Google Scholar 

  17. Ol’khov, Yu.A., Allayarov, S.R., and Belov, G.P., High Energy Chem., 2012, vol. 46, no. 3, p. 148.

    Article  Google Scholar 

  18. Olkhov, Y.A. and Jurkovski, B., J. Therm. Anal. Calorim., 2005, vol. 81, p. 489.

    Article  CAS  Google Scholar 

  19. Jurkowski, B. and Olkhov, Y.A., Thermochim. Acta, 2004, vol. 414, p. 243.

    Article  CAS  Google Scholar 

  20. Pesetskii, S.S., Jurkovski, B., Olkhov, Y.A., Olkhova, O.M., Storozhuk, I.P., and Mozheiko, U.M., Eur. Polym. J., 2001, vol. 37, p. 2187.

    Article  CAS  Google Scholar 

  21. Ol’khov, Yu.A., Allayarov, S.R., Kochetkova, G.V., and Dixon, D.A., Plast. Massy, 2010, p. 4.

    Google Scholar 

  22. Vorovich, I.I. and Ustinov, Iu.A., J. Appl. Math. Mech., vol. 23, 1959, p. 445.

    Google Scholar 

  23. Bunkin, F.V, Kirichenko, N.A., and Luk’yanchuk, B.S., Usp. Fiz. Nauk, 1982, vol. 138, p. 45.

    Article  CAS  Google Scholar 

  24. Tolstopyatov, E.M., Grakovich, P.N., and Ivanov, L.F., Vests. Akad. Navuk BSSR, Ser. Khim. Navuk. 1989, p. 23.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    O. N. Golodkov, Yu. A. Ol’khov, S. R. Allayarov & G. P. Belov

  2. Institute of Mechanics of Metal-Polymer Systems, National Academy of Sciences of Belarus, ul. Kirova 32a, Gomel, 246050, Belarus

    P. N. Grakovich, L. F. Ivanov & L. A. Kalinin

  3. Department of Chemistry, Alabama University, Tuscaloosa, Alabama, 35487-0336, USA

    D. A. Dixon

Authors
  1. O. N. Golodkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. A. Ol’khov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. R. Allayarov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. N. Grakovich
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. P. Belov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. F. Ivanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. L. A. Kalinin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. D. A. Dixon
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. R. Allayarov.

Additional information

Original Russian Text © O.N. Golodkov, Yu.A. Ol’khov, S.R. Allayarov, P.N. Grakovich, G.P. Belov, L.F. Ivanov, L.A. Kalinin, D.A. Dixon, 2013, published in Khimiya Vysokikh Energii, 2013, Vol. 47, No. 3, pp. 171–177.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Golodkov, O.N., Ol’khov, Y.A., Allayarov, S.R. et al. The effect of γ-irradiation on laser ablation of polyketone. High Energy Chem 47, 77–82 (2013). https://doi.org/10.1134/S001814391303003X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S001814391303003X

Keywords

Search

Navigation