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Isothermal Photo Differential Scanning Calorimetry. Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators

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Abstract

The effect of photoinitating (camphorquinone/amines) system concentration and sample thickness on the photopolymerization of triethyleneglycol dimethacrylate/2-hydroxypropyl methacrylate has been investigated. The rate of photopolymerization reaches a maximum and then decreases as the concentration of photoinitiating system increases. This effect has been intepreted as inner filter effect.

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References

  1. J. F. Rabek in ‘Radiation Curing in Polymer Science and Technology: Fundamentals and Methods’, (Eds J. P. Fouassier and J. F. Rabek), Vol. I, Elsevier Applied Science, London 1993, p. 371 and references cited there.

    Google Scholar 

  2. Z. Kucybala, M. Pietrzak, J. Paczkowski, L. Å. Lindén and J. F. Rabek, Polymer, 37 (1996) 3585.

    Article  Google Scholar 

  3. J. Nie, L. Å. Lindén, J. F. Rabek, J. P. Fouassier, F. Morlet-Savary, F. Scigalski, A. Wrzyszczynski and E. Andrzejewska, Acta Polym., 49 (1998) 145.

    Article  CAS  Google Scholar 

  4. E. Andrzejewska, L. Å. Lindén and J. F. Rabek, Polym. Intern., 42 (1997) 179.

    Article  CAS  Google Scholar 

  5. E. Andrzejewska, L. Å. Lindén and J. F. Rabek, Macromol. Chem. Phys., 199 (1998) 441.

    CAS  Google Scholar 

  6. E. Andrzejewska, M. Andrzejewski, L. Å. Lindén and J. F. Rabek, Polimery, 43 (1998) 427.

    Google Scholar 

  7. J. Nie, E. Andrzejewska, J. F. Rabek, L. Å. Lindén, J. P. Fouassier, J. Paczkowski, F. Scigalski and A. Wrzyszczynski, Macromol. Chem. Phys., 200 (1999) 1692.

    Article  CAS  Google Scholar 

  8. A. Sionkowska, A. Kaminska, L. Å. Lindén and J. F. Rabek, Polym. Bull., 43 (1999) 349.

    Article  CAS  Google Scholar 

  9. J. Jakubiak, J. Nie, L. Å. Lindén and J. F. Rabek, J. Polym. Sci., Part A. Polym. Chem., 38 (2000) 876.

    Article  CAS  Google Scholar 

  10. J. F. Rabek, J. P. Fouassier, L. Å. Lindén, J. Nie, E. Andrzejewska, J. Jakubiak, J. Paczkowski, A. Wrzyszczynski and A. Sionkowska, Trends Photochem. Photobiol., 5 (1999) 51.

    CAS  Google Scholar 

  11. W. D. Cook, J. Dent. Res., 59 (1980) 800.

    CAS  Google Scholar 

  12. W. D. Cook, J. Dent Res., 61 (1982) 1436.

    CAS  Google Scholar 

  13. W. D. Cook, J. Appl. Polym. Sci., 42 (1991) 2209.

    Article  CAS  Google Scholar 

  14. W. D. Cook, Polymer, 33 (1992) 600.

    Article  CAS  Google Scholar 

  15. W. D. Cook, Polymer, 33 (1992) 2152.

    Article  CAS  Google Scholar 

  16. W. D. Cook, J. Polym. Sci., A1, 31 (1993) 1053.

    Article  CAS  Google Scholar 

  17. J. Jakubiak, A. Sionkowska, L. Å. Lindén and J. F. Rabek (in preparation for publication).

  18. R. M. Joshe, Makromol. Chem., 66 (1969) 114.

    Article  Google Scholar 

  19. F. H. Sawada, J. Macromol. Sci., C3 (1969) 313.

    Google Scholar 

  20. F. R. Wright, J. Polym. Sci., B16 (1978) 121.

    Google Scholar 

  21. K. S. Anseth, S. M. Newman and C. N. Bowman, Adv. Polym. Sci., 122 (1995) 179.

    Google Scholar 

  22. J. Jakubiak and J. F. Rabek, Polimery, 45 (2000) 501, 593 and 46 (2001) 10.

    Google Scholar 

  23. J. Hutchison and A. Ledwith, Polymer, 14 (1973) 405.

    Article  Google Scholar 

  24. J. Guthrie, M. B. Jegenathan, M. S. Otterbrun and J. Woods, Polym. Bull., 15 (1986) 51.

    Article  CAS  Google Scholar 

  25. K. Seko, Proc. Conf. Rad. Tech. Asia, Tokyo, Japan 1986, p. 331.

  26. L. R. Gatechair, Proc. Conf. Rad. Tech. North America, New Orleans, USA 1988, p. 28.

    Google Scholar 

  27. L. R. Gatechair and A. M. Tiefenhaler, ACS Symp., 417 (1990) 27.

    Article  CAS  Google Scholar 

  28. G. R. Tryson and A. R. Shultz, J. Polym. Sci., Phys. Ed., 17 (1979) 2059.

    Article  CAS  Google Scholar 

  29. F. A. Rueggeberg, W. F. Caughman and J. W. Curtis, Jr. Oper. Dent., 19 (1994) 26.

    CAS  Google Scholar 

  30. J. Jakubiak and L. Å. Lindén, Polimery Polymery, 46 (2001) 530, 588.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Jagiellonian University, Ingardena 3, PL-30 060, Cracow, Poland

    J. Jakubiak

  2. Department of Chemistry, Copernicus University, Gagarina 8, PL 87-100, Torun, Poland

    A. Sionkowska

  3. Polymer Research Group, Department of Dental Biomaterial Science, Karolinska Institute, Box 4064, S-141 04, Huddinge, Stockholm, Sweden

    L.-Å. Lindén & J. F. Rabek

  4. Department of Chemistry and Chemical Engineering, Technical and Agricultural University, Seminaryjna 3, 85-326, Bydgoszcz, Poland

    J. F. Rabek

Authors
  1. J. Jakubiak
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  2. A. Sionkowska
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  3. L.-Å. Lindén
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  4. J. F. Rabek
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Jakubiak, J., Sionkowska, A., Lindén, LÅ. et al. Isothermal Photo Differential Scanning Calorimetry. Crosslinking polymerization of multifunctional monomers in presence of visible light photoinitiators. Journal of Thermal Analysis and Calorimetry 65, 435–443 (2001). https://doi.org/10.1023/A:1012424918321

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