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Synthesis and structure of the first ribbed-functionalized quinoxaline clathrochelate: design of cage complexes for efficient intercalation into DNA structure

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Abstract

Condensation of the dichloride clathrochelate FeBd2(Cl2Gm)(BF)2 precursor (Bd2– is the α-benzyl dioxime dianion, Gm is the glyoxime residue) with quinoxaline-2,3-dithiol in the presence of triethylamine afforded the ribbed-functionalized quinoxaline clathrochelate. The structure of this complex was established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation, Russia

    Ya. Z. Voloshin, M. Yu. Antipin & Z. A. Starikova

  2. L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 105064 Moscow, Russian Federation, Russia

    Ya. Z. Voloshin, A. S. Belov, A. Yu. Lebedev & T. E. Kron

  3. V. I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 32/34 ul. Palladina, 03680 Kiev, Ukraine

    O. A. Varzatskii

Authors
  1. Ya. Z. Voloshin
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  2. A. S. Belov
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  3. A. Yu. Lebedev
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  4. O. A. Varzatskii
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  5. M. Yu. Antipin
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  6. Z. A. Starikova
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  7. T. E. Kron
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Voloshin, Y.Z., Belov, A.S., Lebedev, A.Y. et al. Synthesis and structure of the first ribbed-functionalized quinoxaline clathrochelate: design of cage complexes for efficient intercalation into DNA structure. Russian Chemical Bulletin 53, 1218–1222 (2004). https://doi.org/10.1023/B:RUCB.0000042276.31796.ca

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  • DOI: https://doi.org/10.1023/B:RUCB.0000042276.31796.ca

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